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3-((4aS,6aR,7R,7aS,10R,11aS,13R,13aR,13bR)-7-hydroxy-10-methyl-2,3,4,4a,6a,7,7a,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-7,13-methanonaphtho[2',1':4,5]cyclohepta[1,2-b]pyridin-5-yl)oxazolidin-2-one
CAS号:901121-92-4
英文名:3-((4aS,6aR,7R,7aS,10R,11aS,13R,13aR,13bR)-7-hydroxy-10-methyl-2,3,4,4a,6a,7,7a,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-7,13-methanonaphtho[2',1':4,5]cyclohepta[1,2-b]pyridin-5-yl)oxazolidin-2-one
分子式:C23H34N2O3
分子量:386.528
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合成路线
901121-77-5
(+/-)-(2E,4Z)-(4-bromo-1-methyl-undeca-2,4,10-trienyloxy)-tert-butyl-dimethyl-silane
901121-92-4
3-((4aS,6aR,7R,7aS,10R,11aS,13R,13aR,13bR)-7-hydroxy-10-methyl-2,3,4,4a,6a,7,7a,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-7,13-methanonaphtho[2',1':4,5]cyclohepta[1,2-b]pyridin-5-yl)oxazolidin-2-one
901121-85-5
(+/-)-3-[(1Z)-1-((E)-3-hydroxy-but-1-enyl)-octa-1,7-dienyl]-oxazolidin-2-one
901121-92-4
3-((4aS,6aR,7R,7aS,10R,11aS,13R,13aR,13bR)-7-hydroxy-10-methyl-2,3,4,4a,6a,7,7a,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-7,13-methanonaphtho[2',1':4,5]cyclohepta[1,2-b]pyridin-5-yl)oxazolidin-2-one
901121-78-6
(+/-)-3-{(1Z)-1-[(E)-(3-tert-butyl-dimethyl-silanyloxy)-but-1-enyl]-octa-1,7-dienyl}-oxazolidin-2-one
901121-92-4
3-((4aS,6aR,7R,7aS,10R,11aS,13R,13aR,13bR)-7-hydroxy-10-methyl-2,3,4,4a,6a,7,7a,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-7,13-methanonaphtho[2',1':4,5]cyclohepta[1,2-b]pyridin-5-yl)oxazolidin-2-one
901121-79-7
3-{(1Z)-1-[(Z)-3-(tert-butyl-dimethyl-silanyloxy)-but-1,3-dienyl]-octa-1,7-dienyl}-oxazolidin-2-one
901121-92-4
3-((4aS,6aR,7R,7aS,10R,11aS,13R,13aR,13bR)-7-hydroxy-10-methyl-2,3,4,4a,6a,7,7a,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-7,13-methanonaphtho[2',1':4,5]cyclohepta[1,2-b]pyridin-5-yl)oxazolidin-2-one
901121-88-8
(-)-(R)-(1-methyl-5-oxo-hexyl)-carbamic acid tert-butyl ester
901121-92-4
3-((4aS,6aR,7R,7aS,10R,11aS,13R,13aR,13bR)-7-hydroxy-10-methyl-2,3,4,4a,6a,7,7a,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-7,13-methanonaphtho[2',1':4,5]cyclohepta[1,2-b]pyridin-5-yl)oxazolidin-2-one
901121-80-0
(2E,8Z,10E)-12-(tert-butyl-dimethyl-silanyloxy)-9-(2-oxo-oxazolidin-3-yl)-trideca-2,8,10,12-tetraen-1-al
901121-92-4
3-((4aS,6aR,7R,7aS,10R,11aS,13R,13aR,13bR)-7-hydroxy-10-methyl-2,3,4,4a,6a,7,7a,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-7,13-methanonaphtho[2',1':4,5]cyclohepta[1,2-b]pyridin-5-yl)oxazolidin-2-one
上游原料
(+/-)-3-[(1Z)-1-((E)-3-hydroxy-but-1-enyl)-octa-1,7-dienyl]-oxazolidin-2-one
(+/-)-(2E,4Z)-(4-bromo-1-methyl-undeca-2,4,10-trienyloxy)-tert-butyl-dimethyl-silane
(+/-)-3-{(1Z)-1-[(E)-(3-tert-butyl-dimethyl-silanyloxy)-but-1-enyl]-octa-1,7-dienyl}-oxazolidin-2-one
3-{(1Z)-1-[(Z)-3-(tert-butyl-dimethyl-silanyloxy)-but-1,3-dienyl]-octa-1,7-dienyl}-oxazolidin-2-one
(-)-(R)-(1-methyl-5-oxo-hexyl)-carbamic acid tert-butyl ester
(2E,8Z,10E)-12-(tert-butyl-dimethyl-silanyloxy)-9-(2-oxo-oxazolidin-3-yl)-trideca-2,8,10,12-tetraen-1-al
下游产品
(+)-N-Cbz-galbulimima alkaloid 13