百科

methyl (2E,3E,5E,9E)-2-ethylidene-4,10-dimethyl-11-tert-butyldimethylsilyloxy-3,5,9-undecatrienoate

methyl (2E,3E,5E,9E)-2-ethylidene-4,10-dimethyl-11-tert-butyldimethylsilyloxy-3,5,9-undecatrienoate

CAS号：902798-77-0

英文名：methyl (2E,3E,5E,9E)-2-ethylidene-4,10-dimethyl-11-tert-butyldimethylsilyloxy-3,5,9-undecatrienoate

分子式：C22H38O3Si

分子量：378.621

合成路线

E-2-methyl-7-trimethylsilyl-2-buten-6-yn-1-ol

E-2-methyl-7-trimethylsilyl-2-buten-6-yn-1-ol

methyl (2E,3E,5E,9E)-2-ethylidene-4,10-dimethyl-11-tert-butyldimethylsilyloxy-3,5,9-undecatrienoate

methyl (2E,3E,5E,9E)-2-ethylidene-4,10-dimethyl-11-tert-butyldimethylsilyloxy-3,5,9-undecatrienoate

2-methyl-2,6-nonadien-8-yn-1-ol

2-methyl-2,6-nonadien-8-yn-1-ol

methyl (2E,3E,5E,9E)-2-ethylidene-4,10-dimethyl-11-tert-butyldimethylsilyloxy-3,5,9-undecatrienoate

methyl (2E,3E,5E,9E)-2-ethylidene-4,10-dimethyl-11-tert-butyldimethylsilyloxy-3,5,9-undecatrienoate

(E)-2-methyl-hept-2-en-6-yn-1-ol

(E)-2-methyl-hept-2-en-6-yn-1-ol

methyl (2E,3E,5E,9E)-2-ethylidene-4,10-dimethyl-11-tert-butyldimethylsilyloxy-3,5,9-undecatrienoate

methyl (2E,3E,5E,9E)-2-ethylidene-4,10-dimethyl-11-tert-butyldimethylsilyloxy-3,5,9-undecatrienoate

(E,E,E)-9-tert-butyldimethylsilyloxy-1-iodo-2,8-dimethyl-1,3,7-nonatriene

(E,E,E)-9-tert-butyldimethylsilyloxy-1-iodo-2,8-dimethyl-1,3,7-nonatriene

methyl (Z)-2-iodo-2-butenoate

methyl (Z)-2-iodo-2-butenoate

methyl (2E,3E,5E,9E)-2-ethylidene-4,10-dimethyl-11-tert-butyldimethylsilyloxy-3,5,9-undecatrienoate

methyl (2E,3E,5E,9E)-2-ethylidene-4,10-dimethyl-11-tert-butyldimethylsilyloxy-3,5,9-undecatrienoate

上游原料

(E)-2-methyl-hept-2-en-6-yn-1-ol methyl (Z)-2-iodo-2-butenoate 2-methyl-2,6-nonadien-8-yn-1-ol E-2-methyl-7-trimethylsilyl-2-buten-6-yn-1-ol (E,E,E)-9-tert-butyldimethylsilyloxy-1-iodo-2,8-dimethyl-1,3,7-nonatriene

下游产品

(1S,4S,5S)-4-methyl-1-[(2E,6E,8E,10E)-2,8-dimethyl-1-hydroxy-10-methoxycarbonyldodeca-2,6,10-trienyl]-3,6-dioxabicyclo[3.1.0]hexan-2-one