rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

CAS号：90344-12-0

英文名：rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

分子式：C14H22O3

分子量：238.323

合成路线

(3aR,4R,7S,7aS)-4-(3-Benzenesulfonyl-propyl)-7-methyl-3a,4,7,7a-tetrahydro-isobenzofuran-1,3-dione

(3aR,4R,7S,7aS)-4-(3-Benzenesulfonyl-propyl)-7-methyl-3a,4,7,7a-tetrahydro-isobenzofuran-1,3-dione

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

(E,E)-octa-4,6-dien-1-ol tosylate

(E,E)-octa-4,6-dien-1-ol tosylate

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

(E,E)-4,6-octadienyl phenyl sulfone

(E,E)-4,6-octadienyl phenyl sulfone

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

rac-methyl (4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-8-carboxylate

rac-methyl (4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-8-carboxylate

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

(1R,2R,4aS,8aR)-2-Methyl-8-oxo-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester

(1R,2R,4aS,8aR)-2-Methyl-8-oxo-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

dimethyl 2-[(2E,4E)-hexa-2,4-dienyl]propanedioate

dimethyl 2-[(2E,4E)-hexa-2,4-dienyl]propanedioate

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

rac-((4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-8-yl)methanol

上游原料

(1R,2R,4aS,8aR)-2-Methyl-8-oxo-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester rac-methyl (4aR,7S,8S,8aS)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-8-carboxylate (3aR,4R,7S,7aS)-4-(3-Benzenesulfonyl-propyl)-7-methyl-3a,4,7,7a-tetrahydro-isobenzofuran-1,3-dione (E,E)-octa-4,6-dien-1-ol tosylate (E,E)-4,6-octadienyl phenyl sulfone dimethyl 2-[(2E,4E)-hexa-2,4-dienyl]propanedioate

下游产品

rac-(4aR,7S,8S,8aS)-7-methyl-8-((phenylsulfonyl)methyl)-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dithiane] 8-{1-Benzenesulfonyl-2-[(2S,4R,6R)-4-(tert-butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-2-yl]-ethyl}-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-naphthalen-1-one