百科

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

CAS号：90432-98-7

英文名：(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

分子式：C14H20O3

分子量：236.307

合成路线

(2S,3S)-3-tert-butyldimethylsilyloxy-3-(4,5-dimethylfuryl)-2-methylpropionaldehyde

(2S,3S)-3-tert-butyldimethylsilyloxy-3-(4,5-dimethylfuryl)-2-methylpropionaldehyde

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

3-<(4,5-dimethylfuryl)-3'S-hydroxy-2'S-methylpropionyl>-4S-(isopropyl)-2-oxazolidin-2-one

3-<(4,5-dimethylfuryl)-3'S-hydroxy-2'S-methylpropionyl>-4S-(isopropyl)-2-oxazolidin-2-one

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

(1S,2R,3R,4R)-1-tert-butyldimethylsilyloxy-1-(4,5-dimethylfuryl)-2,4-dimethyl-5-hexen-3-ol

(1S,2R,3R,4R)-1-tert-butyldimethylsilyloxy-1-(4,5-dimethylfuryl)-2,4-dimethyl-5-hexen-3-ol

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

(1S,2R,3R,4R)-1-(4,5-dimethylfuryl)-2,4-dimethyl-5-hexen-1,3-diol

(1S,2R,3R,4R)-1-(4,5-dimethylfuryl)-2,4-dimethyl-5-hexen-1,3-diol

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

90432-94-3

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

(1S,3R,4R,5S)-3-<(3'R)-1'-buten-3'-yl>-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-one

上游原料

3-<(4,5-dimethylfuryl)-3'S-hydroxy-2'S-methylpropionyl>-4S-(isopropyl)-2-oxazolidin-2-one (2S,3S)-3-tert-butyldimethylsilyloxy-3-(4,5-dimethylfuryl)-2-methylpropionaldehyde (1S,2R,3R,4R)-1-tert-butyldimethylsilyloxy-1-(4,5-dimethylfuryl)-2,4-dimethyl-5-hexen-3-ol (1S,2R,3R,4R)-1-(4,5-dimethylfuryl)-2,4-dimethyl-5-hexen-1,3-diol

下游产品

ethyl 4(R)-<(1R)-3(S),4,8(R)-trimethyl-6-oxo-2,9-dioxabicyclo-<3.3.1>non-4(Z)-en-1-yl>-2-methylpent-2(E)-enoate