百科

(1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'S)-1'-hydroxy-2'-(triethylsilyloxy)propyl]-4-vinylcyclohexan-2-ol

(1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'S)-1'-hydroxy-2'-(triethylsilyloxy)propyl]-4-vinylcyclohexan-2-ol

CAS号：905312-43-8

英文名：(1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'S)-1'-hydroxy-2'-(triethylsilyloxy)propyl]-4-vinylcyclohexan-2-ol

分子式：C30H54O5Si2

分子量：550.918

合成路线

(4R,6S)-6-benzyloxy-4-[(tert-butyldimethylsilyl)oxy]-2-cyclohexenone

(4R,6S)-6-benzyloxy-4-[(tert-butyldimethylsilyl)oxy]-2-cyclohexenone

(1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'S)-1'-hydroxy-2'-(triethylsilyloxy)propyl]-4-vinylcyclohexan-2-ol

(1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'S)-1'-hydroxy-2'-(triethylsilyloxy)propyl]-4-vinylcyclohexan-2-ol

(S)-2-<(triethylsilyl)oxy>-2-propanal

(S)-2-<(triethylsilyl)oxy>-2-propanal

(1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'S)-1'-hydroxy-2'-(triethylsilyloxy)propyl]-4-vinylcyclohexan-2-ol

(1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'S)-1'-hydroxy-2'-(triethylsilyloxy)propyl]-4-vinylcyclohexan-2-ol

上游原料

(S)-2-<(triethylsilyl)oxy>-2-propanal (4R,6S)-6-benzyloxy-4-[(tert-butyldimethylsilyl)oxy]-2-cyclohexenone

下游产品

Toluene-4-sulfonic acid (1R,3S,4R,4aR,5S,6S,8R,8aR)-6-benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-5-methoxymethoxy-3-methyl-octahydro-isochromen-4-yl ester N-benzyloxycarbonyl-(-)-actinobolin (1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'S)-1'-(p-toluenesulfonyloxy)-2'-(triethylsilyloxy)propyl]-2-methoxymethyloxy-4-vinylcyclohexane (3S,4S,5S,6S,10S)-4-azido-6-benzyloxy-5,8-dihydroxy-3-methyl-5,6,7,4a-tetrahydroisochroman-1-one (3S,4R,4aS,5S,6S,8R,8aR)-6-benzyloxy-8-(tert-butyldimethylsilyloxy)-5-methoxymethyloxy-3-methyl-4-(p-toluenesulfonyloxy)-perhydroisochroman-1-one