百科

[(2R,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-methanol

[(2R,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-methanol

CAS号：909544-81-6

英文名：[(2R,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-methanol

分子式：C12H25ClO3Si

分子量：280.864

合成路线

(2R,3R,4S)-4-Chloro-2-hydroxymethyl-tetrahydro-pyran-3-ol

(2R,3R,4S)-4-Chloro-2-hydroxymethyl-tetrahydro-pyran-3-ol

[(2R,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-methanol

[(2R,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-methanol

(2R,4aR,8S,8aR)-8-Chloro-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

(2R,4aR,8S,8aR)-8-Chloro-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

[(2R,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-methanol

[(2R,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-methanol

1,5-Anhydro-2-deoxy-4,6-O-(phenylmethylene)-D-arabino-hexopyranoside

1,5-Anhydro-2-deoxy-4,6-O-(phenylmethylene)-D-arabino-hexopyranoside

[(2R,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-methanol

[(2R,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-methanol

上游原料

1,5-Anhydro-2-deoxy-4,6-O-(phenylmethylene)-D-arabino-hexopyranoside (2R,4aR,8S,8aR)-8-Chloro-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine (2R,3R,4S)-4-Chloro-2-hydroxymethyl-tetrahydro-pyran-3-ol

下游产品

(2S,3S,4aR,8S,8aR,2'R,4'aS,6'R,7'S,8'S,8'aS)-7',8'-Bis-benzyloxy-6'-benzyloxymethyl-8-chloro-2-methoxy-hexadecahydro-[2,2']bi[pyrano[3,2-b]pyranyl]-3-ol (2S,3S,4aR,8S,8aR,2'R,4'aS,6'R,7'S,8'S,8'aS)-7',8'-Bis-benzyloxy-6'-benzyloxymethyl-8-chloro-dodecahydro-[2,2']bi[pyrano[3,2-b]pyranyl]-2,3-diol 1-[(2S,3S,4S,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-6-[(2R,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-hex-4-yn-3-ol (2S,3R,4aR,8S,8aR,2'R,4'aS,6'R,7'S,8'S,8'aS)-7',8'-Bis-benzyloxy-6'-benzyloxymethyl-8-chloro-2-methoxy-hexadecahydro-[2,2']bi[pyrano[3,2-b]pyranyl]-3-ol (2R,4aR,8S,8aR,2'R,4'aS,6'R,7'S,8'S,8'aS)-7',8'-Bis-benzyloxy-6'-benzyloxymethyl-8-chloro-dodecahydro-[2,2']bi[pyrano[3,2-b]pyranyl]-3-one (2S,3R,4aR,8S,8aR,2'R,4'aS,6'R,7'S,8'S,8'aS)-7',8'-Bis-benzyloxy-6'-benzyloxymethyl-8-chloro-dodecahydro-[2,2']bi[pyrano[3,2-b]pyranyl]-2,3-diol {(2R,3R,4S)-2-[3-((2R,4aS,6R,7S,8S,8aS)-7,8-Bis-benzyloxy-6-benzyloxymethyl-octahydro-pyrano[3,2-b]pyran-2-yl)-prop-2-ynyl]-4-chloro-tetrahydro-pyran-3-yloxy}-tert-butyl-dimethyl-silane (2S,3S,4aR,8S,8aR,2'R,4'aS,6'R,7'S,8'S,8'aS)-7',8'-Bis-benzyloxy-6'-benzyloxymethyl-8-chloro-hexadecahydro-[2,2']bi[pyrano[3,2-b]pyranyl]-3-ol {(2R,3R,4S)-2-[(Z)-3-((2R,4aS,6R,7S,8S,8aS)-7,8-Bis-benzyloxy-6-benzyloxymethyl-octahydro-pyrano[3,2-b]pyran-2-yl)-allyl]-4-chloro-tetrahydro-pyran-3-yloxy}-tert-butyl-dimethyl-silane 1-[(2S,3S,4S,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-6-[(2R,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-hex-4-yn-3-one 1-((2R,4aS,6R,7S,8S,8aS)-7,8-Bis-benzyloxy-6-benzyloxymethyl-octahydro-pyrano[3,2-b]pyran-2-yl)-3-[(2R,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-chloro-tetrahydro-pyran-2-yl]-propane-1,2-diol (2R,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-chloro-2-(3-trimethylsilanyl-prop-2-ynyl)-tetrahydro-pyran tert-Butyl-((2R,3R,4S)-4-chloro-2-prop-2-ynyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane (2R,3R,4S)-2-[3-((2R,4aS,6R,7S,8S,8aS)-7,8-Bis-benzyloxy-6-benzyloxymethyl-octahydro-pyrano[3,2-b]pyran-2-yl)-prop-2-ynyl]-4-chloro-tetrahydro-pyran-3-ol