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(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

CAS号：909911-37-1

英文名：(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

分子式：C14H24O3Si

分子量：268.424

合成路线

(3R,3aS,6aR)-3-(hydroxymethyl)-6a-(phenylthio)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

(3R,3aS,6aR)-3-(hydroxymethyl)-6a-(phenylthio)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

tert-butyl (3S)-3-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]pent-4-enoate

tert-butyl (3S)-3-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]pent-4-enoate

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

tert-butyl (2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]cyclopent-3-ene-1-carboxylate

tert-butyl (2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]cyclopent-3-ene-1-carboxylate

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

tert-butyl (3R)-2-allyl-3-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]pent-4-enoate

tert-butyl (3R)-2-allyl-3-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]pent-4-enoate

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

tert-butyl (1R,2S)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylthio)cyclopent-3-ene-1-carboxylate

tert-butyl (1R,2S)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylthio)cyclopent-3-ene-1-carboxylate

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

(3S,2'S)-(1',4'-dioxa-spiro[4.5]dec-2'-yl)-pent-4-enoic acid ethyl ester

(3S,2'S)-(1',4'-dioxa-spiro[4.5]dec-2'-yl)-pent-4-enoic acid ethyl ester

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

(3R,3aR,6aS)-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one

上游原料

(3S,2'S)-(1',4'-dioxa-spiro[4.5]dec-2'-yl)-pent-4-enoic acid ethyl ester tert-butyl (3R)-2-allyl-3-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]pent-4-enoate tert-butyl (2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]cyclopent-3-ene-1-carboxylate tert-butyl (1R,2S)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylthio)cyclopent-3-ene-1-carboxylate (3R,3aS,6aR)-3-(hydroxymethyl)-6a-(phenylthio)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one tert-butyl (3S)-3-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]pent-4-enoate

下游产品

(3R,3aS,4S,6aS)-4-hydroxy-3-(tert-butyldimethylsilanyloxymethyl)-3,3a,4,6a-tetrahydro-1H-cyclopenta[c]furan-1-one