百科

(+)-2α-bromomethyl-8aβ-isopropoxycarbonyl-5β-hydroxy-4aβ,5,8,8a-tetrahydro-4H-1,3-benzodioxin-7-carboxylic acid

(+)-2α-bromomethyl-8aβ-isopropoxycarbonyl-5β-hydroxy-4aβ,5,8,8a-tetrahydro-4H-1,3-benzodioxin-7-carboxylic acid

CAS号：910043-03-7

英文名：(+)-2α-bromomethyl-8aβ-isopropoxycarbonyl-5β-hydroxy-4aβ,5,8,8a-tetrahydro-4H-1,3-benzodioxin-7-carboxylic acid

分子式：C14H19BrO7

分子量：379.2

合成路线

tert-butyl (E,E)-6-formylpenta-2,4-dienoate

tert-butyl (E,E)-6-formylpenta-2,4-dienoate

(+)-2α-bromomethyl-8aβ-isopropoxycarbonyl-5β-hydroxy-4aβ,5,8,8a-tetrahydro-4H-1,3-benzodioxin-7-carboxylic acid

(+)-2α-bromomethyl-8aβ-isopropoxycarbonyl-5β-hydroxy-4aβ,5,8,8a-tetrahydro-4H-1,3-benzodioxin-7-carboxylic acid

上游原料

tert-butyl (E,E)-6-formylpenta-2,4-dienoate

下游产品

(+)-isopropyl 2α-bromomethyl-7-(tert-butyldiphenylsilyloxymethyl)-5β-hydroxy-4aβ,5,8,8a-tetrahydro-4H-1,3-benzodioxin-8aβ-carboxylate (+)-isopropyl 3-(tert-butyldiphenylsilyloxymethyl)-6α-(ethenyloxymethoxy)-1α-hydroxy-5β-(methoxymethoxy)-3-cyclohexene-1-carboxylate