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(R)-2-{(2R,5S,6R)-6-[(Z)-1-(tert-Butyl-dimethyl-silanyloxy)-propenyl]-5-methyl-tetrahydro-pyran-2-yl}-propionic acid methyl ester

(R)-2-{(2R,5S,6R)-6-[(Z)-1-(tert-Butyl-dimethyl-silanyloxy)-propenyl]-5-methyl-tetrahydro-pyran-2-yl}-propionic acid methyl ester

CAS号：91053-97-3

英文名：(R)-2-{(2R,5S,6R)-6-[(Z)-1-(tert-Butyl-dimethyl-silanyloxy)-propenyl]-5-methyl-tetrahydro-pyran-2-yl}-propionic acid methyl ester

分子式：C19H36O4Si

分子量：356.572

合成路线

(1S,2R,3S,5R)-2-methyl-6,8-dioxabicyclo<3.2.1>octan-3-yl propanoate

(1S,2R,3S,5R)-2-methyl-6,8-dioxabicyclo<3.2.1>octan-3-yl propanoate

(R)-2-{(2R,5S,6R)-6-[(Z)-1-(tert-Butyl-dimethyl-silanyloxy)-propenyl]-5-methyl-tetrahydro-pyran-2-yl}-propionic acid methyl ester

(R)-2-{(2R,5S,6R)-6-[(Z)-1-(tert-Butyl-dimethyl-silanyloxy)-propenyl]-5-methyl-tetrahydro-pyran-2-yl}-propionic acid methyl ester

(1S,2S,3S,4R,5R)-2-methyl-4-<(p-toluenesulfonyl)-oxy>-6,8-dioxabicyclo<3.2.1>octan-3-ol

(1S,2S,3S,4R,5R)-2-methyl-4-<(p-toluenesulfonyl)-oxy>-6,8-dioxabicyclo<3.2.1>octan-3-ol

(R)-2-{(2R,5S,6R)-6-[(Z)-1-(tert-Butyl-dimethyl-silanyloxy)-propenyl]-5-methyl-tetrahydro-pyran-2-yl}-propionic acid methyl ester

(R)-2-{(2R,5S,6R)-6-[(Z)-1-(tert-Butyl-dimethyl-silanyloxy)-propenyl]-5-methyl-tetrahydro-pyran-2-yl}-propionic acid methyl ester

(2S,3S,4R)-<<3-methyl-4-(propionyloxy)-3,4-dihydro-2H-pyran-2-yl>methoxy>trimethylsilane

(2S,3S,4R)-<<3-methyl-4-(propionyloxy)-3,4-dihydro-2H-pyran-2-yl>methoxy>trimethylsilane

(R)-2-{(2R,5S,6R)-6-[(Z)-1-(tert-Butyl-dimethyl-silanyloxy)-propenyl]-5-methyl-tetrahydro-pyran-2-yl}-propionic acid methyl ester

(R)-2-{(2R,5S,6R)-6-[(Z)-1-(tert-Butyl-dimethyl-silanyloxy)-propenyl]-5-methyl-tetrahydro-pyran-2-yl}-propionic acid methyl ester

上游原料

(2S,3S,4R)-<<3-methyl-4-(propionyloxy)-3,4-dihydro-2H-pyran-2-yl>methoxy>trimethylsilane (1S,2S,3S,4R,5R)-2-methyl-4-<(p-toluenesulfonyl)-oxy>-6,8-dioxabicyclo<3.2.1>octan-3-ol (1S,2R,3S,5R)-2-methyl-6,8-dioxabicyclo<3.2.1>octan-3-yl propanoate

下游产品

methyl α(R),5(S)-dimethyl-6(R)-<1(R)-hydroxypropyl>tetrahydropyran-2(R)-acetate