百科

tert-butyldimethylsilyl (2R,4aS,8aR)-2-(5-((tert-butyldimethylsilyl)oxy)pentyl)hexahydro-2H-pyrano[2,3-b]pyridine-8(5H)-carboxylate

tert-butyldimethylsilyl (2R,4aS,8aR)-2-(5-((tert-butyldimethylsilyl)oxy)pentyl)hexahydro-2H-pyrano[2,3-b]pyridine-8(5H)-carboxylate

CAS号：911483-91-5

英文名：tert-butyldimethylsilyl (2R,4aS,8aR)-2-(5-((tert-butyldimethylsilyl)oxy)pentyl)hexahydro-2H-pyrano[2,3-b]pyridine-8(5H)-carboxylate

分子式：C26H53NO4Si2

分子量：499.874

合成路线

5-Iodo-3,4-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester

5-Iodo-3,4-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester

tert-butyldimethylsilyl (2R,4aS,8aR)-2-(5-((tert-butyldimethylsilyl)oxy)pentyl)hexahydro-2H-pyrano[2,3-b]pyridine-8(5H)-carboxylate

tert-butyldimethylsilyl (2R,4aS,8aR)-2-(5-((tert-butyldimethylsilyl)oxy)pentyl)hexahydro-2H-pyrano[2,3-b]pyridine-8(5H)-carboxylate

(R)-8-(tert-butyldimethylsilyloxy)oct-1-yn-3-ol

(R)-8-(tert-butyldimethylsilyloxy)oct-1-yn-3-ol

tert-butyldimethylsilyl (2R,4aS,8aR)-2-(5-((tert-butyldimethylsilyl)oxy)pentyl)hexahydro-2H-pyrano[2,3-b]pyridine-8(5H)-carboxylate

tert-butyldimethylsilyl (2R,4aS,8aR)-2-(5-((tert-butyldimethylsilyl)oxy)pentyl)hexahydro-2H-pyrano[2,3-b]pyridine-8(5H)-carboxylate

8-(tert-Butyl-dimethyl-silanyloxy)-oct-1-yn-3-one

8-(tert-Butyl-dimethyl-silanyloxy)-oct-1-yn-3-one

tert-butyldimethylsilyl (2R,4aS,8aR)-2-(5-((tert-butyldimethylsilyl)oxy)pentyl)hexahydro-2H-pyrano[2,3-b]pyridine-8(5H)-carboxylate

tert-butyldimethylsilyl (2R,4aS,8aR)-2-(5-((tert-butyldimethylsilyl)oxy)pentyl)hexahydro-2H-pyrano[2,3-b]pyridine-8(5H)-carboxylate

上游原料

8-(tert-Butyl-dimethyl-silanyloxy)-oct-1-yn-3-one (R)-8-(tert-butyldimethylsilyloxy)oct-1-yn-3-ol 5-Iodo-3,4-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester

下游产品

(2R,4aS,8aR)-2-[5-(tert-Butyl-dimethyl-silanyloxy)-pentyl]-octahydro-pyrano[2,3-b]pyridine 5-[(2R,4aS,8aR)-8-((E)-3-Iodo-allyl)-octahydro-pyrano[2,3-b]pyridin-2-yl]-pentan-1-ol (2R,4aS,8aR)-2-[5-(tert-Butyl-dimethyl-silanyloxy)-pentyl]-8-((E)-3-iodo-allyl)-octahydro-pyrano[2,3-b]pyridine