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(Z)-(5S,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-octa-3,7-dien-1-ol

(Z)-(5S,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-octa-3,7-dien-1-ol

CAS号：911834-93-0

英文名：(Z)-(5S,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-octa-3,7-dien-1-ol

分子式：C20H42O3Si2

分子量：386.717

合成路线

tert-Butyl-[(Z)-4-((4S,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-dimethyl-silane

tert-Butyl-[(Z)-4-((4S,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-dimethyl-silane

(Z)-(5S,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-octa-3,7-dien-1-ol

(Z)-(5S,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-octa-3,7-dien-1-ol

(S,S)-2,2-dimethyl-4-[(tert-butyldimethylsilyloxy)methyl]-5-vinyl-1,3-dioxolane

(S,S)-2,2-dimethyl-4-[(tert-butyldimethylsilyloxy)methyl]-5-vinyl-1,3-dioxolane

(Z)-(5S,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-octa-3,7-dien-1-ol

(Z)-(5S,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-octa-3,7-dien-1-ol

上游原料

tert-Butyl-[(Z)-4-((4S,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-but-3-enyloxy]-dimethyl-silane (S,S)-2,2-dimethyl-4-[(tert-butyldimethylsilyloxy)methyl]-5-vinyl-1,3-dioxolane

下游产品

(3Z,9E)-(1R,7S,11S,15S,17R)-7-((E)-(S)-3-Cyclohexyl-1-hydroxy-allyl)-11-hydroxy-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one (Z)-(1R,3S,7S,8S,10S,12S,18R)-12-((E)-(S)-3-Cyclohexyl-1-hydroxy-allyl)-7-hydroxy-3-methyl-5-methylene-9,13,22-trioxa-tricyclo[16.3.1.08,10]docosa-15,19-dien-14-one (2R,6R)-2-[(E)-(2S,6S,10S,11S)-10,11-Bis-(tert-butyl-dimethyl-silanyloxy)-6-methoxymethoxy-2-methyl-4-methylene-trideca-7,12-dienyl]-6-(3-trimethylsilanyl-prop-2-ynyl)-3,6-dihydro-2H-pyran