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(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

CAS号：912457-44-4

英文名：(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

分子式：C32H46O4Si

分子量：522.791

合成路线

dimethyl 3-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}-2-oxopropyl-phosphonate

dimethyl 3-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}-2-oxopropyl-phosphonate

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

ethyl 7-(4-methoxyphenoxy)hept-2-ynoate

ethyl 7-(4-methoxyphenoxy)hept-2-ynoate

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(3E,5Z)-1-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}-5-methylhepta-3,5-dien-2-one

(3E,5Z)-1-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}-5-methylhepta-3,5-dien-2-one

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

ethyl 7-(4-methoxyphenoxy)hepta-2,4-dienoate

ethyl 7-(4-methoxyphenoxy)hepta-2,4-dienoate

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

ethyl 2-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}acetate

ethyl 2-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}acetate

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

6-(4-methoxyphenoxy)hex-1-yne

6-(4-methoxyphenoxy)hex-1-yne

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

N-methoxy-N-methyl-2-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}acetamide

N-methoxy-N-methyl-2-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}acetamide

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R,4R,6R,8R,9S)-4-hydroxy-8,9-dimethyl-2-[2-(4-methoxyphenoxy)ethyl]-1,7-dioxaspiro[5.5]undecane

(2R,4R,6R,8R,9S)-4-hydroxy-8,9-dimethyl-2-[2-(4-methoxyphenoxy)ethyl]-1,7-dioxaspiro[5.5]undecane

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2S,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-2-[2-(4-methoxyphenoxy)ethyl]-1,7-dioxaspiro[5.5]undecane

(2S,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-2-[2-(4-methoxyphenoxy)ethyl]-1,7-dioxaspiro[5.5]undecane

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R,4R,6R,8R,9S)-4-<(tert-butyldiphenylsilyl)oxy>-2-(2-hydroxyethyl)-8,9-dimethyl-1,7-dioxaspiro<5.5>undecane

(2R,4R,6R,8R,9S)-4-<(tert-butyldiphenylsilyl)oxy>-2-(2-hydroxyethyl)-8,9-dimethyl-1,7-dioxaspiro<5.5>undecane

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

(2R)-1-{(2R,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl}-3-methylbut-3-en-2-ol

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上游原料

(E)-3-{(4R,5R)-5-[2-(4-Methoxy-phenoxy)-ethyl]-2-oxo-[1,3]dioxolan-4-yl}-acrylic acid ethyl ester ethyl (5S)-7-(4-methoxyphenoxy)-5-hydroxy-2-heptenoate ethyl 7-(4-methoxyphenoxy)hepta-2,4-dienoate ethyl 7-(4-methoxyphenoxy)hept-2-ynoate (2S,4R,6R,8R,9S)-4-[tert-butyl(diphenyl)silyloxy]-8,9-dimethyl-2-[2-(4-methoxyphenoxy)ethyl]-1,7-dioxaspiro[5.5]undecane (3E,5Z)-1-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}-5-methylhepta-3,5-dien-2-one (2R,4R,6R,8R,9S)-4-hydroxy-8,9-dimethyl-2-[2-(4-methoxyphenoxy)ethyl]-1,7-dioxaspiro[5.5]undecane dimethyl 3-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}-2-oxopropyl-phosphonate (2R,4R,6R,8R,9S)-4-<(tert-butyldiphenylsilyl)oxy>-2-(2-hydroxyethyl)-8,9-dimethyl-1,7-dioxaspiro<5.5>undecane N-methoxy-N-methyl-2-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}acetamide ethyl 2-{(2R,4R,6R)-6-[2-(4-methoxyphenoxy)ethyl]-2-phenyl-1,3-dioxan-4-yl}acetate 6-(4-methoxyphenoxy)hex-1-yne

下游产品

2-<(5R)-9-<(2R,4R,6R,8R,9S)-4-hydroxy-8,9-dimethyl-1,7-dioxaspiro<5.5>undec-1-yl>-1,5,7-trimethyl-1(E),3(E),7(Z)-nonatrien-1-yl>-4-methoxy-5-methylbenzoic acid