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(4'aR,8'aS)-dimethyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]

(4'aR,8'aS)-dimethyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]

CAS号：915315-58-1

英文名：(4'aR,8'aS)-dimethyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]

分子式：C14H22O2

分子量：222.323

合成路线

(S)-octalone

(4'aR,8'aS)-dimethyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]

(4'aR,8'aS)-dimethyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]

(8'aS)-methyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]-(4'aS)-carbonitrile

(8'aS)-methyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]-(4'aS)-carbonitrile

(4'aR,8'aS)-dimethyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]

(4'aR,8'aS)-dimethyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]

(8'aS)-methyl-6'-oxo-octahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]-(4'aS)-carbonitrile

(8'aS)-methyl-6'-oxo-octahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]-(4'aS)-carbonitrile

(4'aR,8'aS)-dimethyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]

(4'aR,8'aS)-dimethyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]

(4aR,8aR)-4a-methyl-4,4a,5,8-tetrahydro-1H-spiro[naphthalene-2,2'-[1,3]dioxolane]-8a(3H)-carbaldehyde

(4aR,8aR)-4a-methyl-4,4a,5,8-tetrahydro-1H-spiro[naphthalene-2,2'-[1,3]dioxolane]-8a(3H)-carbaldehyde

(4'aR,8'aS)-dimethyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]

(4'aR,8'aS)-dimethyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]

上游原料

(4aR,8aR)-4a-methyl-4,4a,5,8-tetrahydro-1H-spiro[naphthalene-2,2'-[1,3]dioxolane]-8a(3H)-carbaldehyde (S)-octalone (8'aS)-methyl-6'-oxo-octahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]-(4'aS)-carbonitrile (8'aS)-methyl-1',3',4',5',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]-(4'aS)-carbonitrile

下游产品

tert-butyl-(2-{(1S,6S)-dimethyl-6-[2-(2-nitrophenylselanyl)-ethyl]-cyclohexa-2,4-dienyl}-ethoxy)-diphenylsilane (7s,8R)-bis-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-7,8-dimethyl-1,4-dioxa-spiro[4,5]decane