百科

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-(4-methoxybenzyloxy)-2-vinyl-3,4-dihydro-2H-pyran

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-(4-methoxybenzyloxy)-2-vinyl-3,4-dihydro-2H-pyran

CAS号：916154-05-7

英文名：(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-(4-methoxybenzyloxy)-2-vinyl-3,4-dihydro-2H-pyran

分子式：C21H32O4Si

分子量：376.562

合成路线

3,6-O-di-tert-butyldimethylsilyl-4-O-p-methoxybenzyl-D-glucal

3,6-O-di-tert-butyldimethylsilyl-4-O-p-methoxybenzyl-D-glucal

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-(4-methoxybenzyloxy)-2-vinyl-3,4-dihydro-2H-pyran

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-(4-methoxybenzyloxy)-2-vinyl-3,4-dihydro-2H-pyran

上游原料

3,6-O-di-tert-butyldimethylsilyl-4-O-p-methoxybenzyl-D-glucal

下游产品

(S)-hept-6-en-2-yl (3R,4S,5S)-5-benzyloxy-3-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate methyl (3R,4R,5S)-3-(tert-butyldimethylsilyloxy)-5-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate (S)-hept-6-en-2-yl (3R,4S,5S)-3-benzoyloxy-5-benzyloxy-4-(p-methoxybenzyloxy)hept-6-enoate (2R,3S,4R)-4-methoxy-3-(4-methoxybenzyloxy)-2-vinyl-3,4-dihydro-2H-pyran (S)-hept-6-en-2-yl (3R,4R,5S)-5-benzyloxy-3-(tert-butyldimethylsilyloxy)-4-(p-methoxybenzyloxy)hept-6-enoate (S)-hept-6-en-2-yl (3R,4S,5S)-3-benzoyloxy-5-benzyloxy-4-hydroxyhept-6-enoate