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methyl (3R,4R,5S)-3-(tert-butyldimethylsilyloxy)-5-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate

methyl (3R,4R,5S)-3-(tert-butyldimethylsilyloxy)-5-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate

CAS号：916154-06-8

英文名：methyl (3R,4R,5S)-3-(tert-butyldimethylsilyloxy)-5-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate

分子式：C22H36O6Si

分子量：424.603

合成路线

((2R,3R,4R)-4-((tert-butyldimethylsilyl)oxy)-3-((4-methoxybenzyl)oxy)-3,4-dihydro-2H-pyran-2-yl)methanol

((2R,3R,4R)-4-((tert-butyldimethylsilyl)oxy)-3-((4-methoxybenzyl)oxy)-3,4-dihydro-2H-pyran-2-yl)methanol

methyl (3R,4R,5S)-3-(tert-butyldimethylsilyloxy)-5-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate

methyl (3R,4R,5S)-3-(tert-butyldimethylsilyloxy)-5-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate

3,6-O-di-tert-butyldimethylsilyl-4-O-p-methoxybenzyl-D-glucal

3,6-O-di-tert-butyldimethylsilyl-4-O-p-methoxybenzyl-D-glucal

methyl (3R,4R,5S)-3-(tert-butyldimethylsilyloxy)-5-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate

methyl (3R,4R,5S)-3-(tert-butyldimethylsilyloxy)-5-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-(4-methoxybenzyloxy)-2-vinyl-3,4-dihydro-2H-pyran

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-(4-methoxybenzyloxy)-2-vinyl-3,4-dihydro-2H-pyran

methyl (3R,4R,5S)-3-(tert-butyldimethylsilyloxy)-5-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate

methyl (3R,4R,5S)-3-(tert-butyldimethylsilyloxy)-5-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate

上游原料

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-(4-methoxybenzyloxy)-2-vinyl-3,4-dihydro-2H-pyran ((2R,3R,4R)-4-((tert-butyldimethylsilyl)oxy)-3-((4-methoxybenzyl)oxy)-3,4-dihydro-2H-pyran-2-yl)methanol 3,6-O-di-tert-butyldimethylsilyl-4-O-p-methoxybenzyl-D-glucal

下游产品

(S)-hept-6-en-2-yl (3R,4S,5S)-5-benzyloxy-3-hydroxy-4-(p-methoxybenzyloxy)hept-6-enoate (S)-hept-6-en-2-yl (3R,4S,5S)-3-benzoyloxy-5-benzyloxy-4-hydroxyhept-6-enoate