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(2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-one

(2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-one

CAS号：918310-86-8

英文名：(2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-one

分子式：C26H44O4Si2

分子量：476.796

合成路线

(R)-1-iodo-2-methyl-5-(trimethyl)silyl-4-pentyne

(R)-1-iodo-2-methyl-5-(trimethyl)silyl-4-pentyne

(2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-one

(2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-one

(2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-ol

(2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-ol

(2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-one

(2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-one

(S)-4-benzyl-3-((R)-2-methyl-5-(trimethylsilyl)pent-4-ynoyl)oxazolidin-2-one

(S)-4-benzyl-3-((R)-2-methyl-5-(trimethylsilyl)pent-4-ynoyl)oxazolidin-2-one

(2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-one

(2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-one

上游原料

(R)-1-iodo-2-methyl-5-(trimethyl)silyl-4-pentyne (S)-4-benzyl-3-((R)-2-methyl-5-(trimethylsilyl)pent-4-ynoyl)oxazolidin-2-one (2S,5R)-1-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-3-ol

下游产品

(2S,3R,5R)-3-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-ynal (2R,4S,7R,8R,9R,11R)-1-azido-9-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4,11-trimethyl-7-(triethylsilyloxy)-14-(trimethylsilyl)tetradec-13-yn-5-one (2S,3R,5R)-3-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)-5-methyl-8-(trimethylsilyl)oct-7-yn-1-ol