百科

methyl 2-((1E)-3-{(2R,3R,5S,6S)-3-((1S,5R)-5-hydroxy)-1-(methyloxymethyl)oxy-hexyl-5,6-bis[4-(methyloxy)phenyl]-1,4-dioxan-2-yl}-1-propenyl) benzoate

methyl 2-((1E)-3-{(2R,3R,5S,6S)-3-((1S,5R)-5-hydroxy)-1-(methyloxymethyl)oxy-hexyl-5,6-bis[4-(methyloxy)phenyl]-1,4-dioxan-2-yl}-1-propenyl) benzoate

CAS号：918328-71-9

英文名：methyl 2-((1E)-3-{(2R,3R,5S,6S)-3-((1S,5R)-5-hydroxy)-1-(methyloxymethyl)oxy-hexyl-5,6-bis[4-(methyloxy)phenyl]-1,4-dioxan-2-yl}-1-propenyl) benzoate

分子式：C37H46O9

分子量：634.756

合成路线

(3S,5S,6S)-3-[(1S,5R)-5-(tert-butyldiphenylsilyloxy)-1-(methoxymethoxy)hexyl]-5,6-bis-(4-methoxyphenyl)-[1,4]-dioxan-2-one

(3S,5S,6S)-3-[(1S,5R)-5-(tert-butyldiphenylsilyloxy)-1-(methoxymethoxy)hexyl]-5,6-bis-(4-methoxyphenyl)-[1,4]-dioxan-2-one

methyl 2-((1E)-3-{(2R,3R,5S,6S)-3-((1S,5R)-5-hydroxy)-1-(methyloxymethyl)oxy-hexyl-5,6-bis[4-(methyloxy)phenyl]-1,4-dioxan-2-yl}-1-propenyl) benzoate

methyl 2-((1E)-3-{(2R,3R,5S,6S)-3-((1S,5R)-5-hydroxy)-1-(methyloxymethyl)oxy-hexyl-5,6-bis[4-(methyloxy)phenyl]-1,4-dioxan-2-yl}-1-propenyl) benzoate

1,2-di(p-methoxyphenyl)ethylene

1,2-di(p-methoxyphenyl)ethylene

methyl 2-((1E)-3-{(2R,3R,5S,6S)-3-((1S,5R)-5-hydroxy)-1-(methyloxymethyl)oxy-hexyl-5,6-bis[4-(methyloxy)phenyl]-1,4-dioxan-2-yl}-1-propenyl) benzoate

methyl 2-((1E)-3-{(2R,3R,5S,6S)-3-((1S,5R)-5-hydroxy)-1-(methyloxymethyl)oxy-hexyl-5,6-bis[4-(methyloxy)phenyl]-1,4-dioxan-2-yl}-1-propenyl) benzoate

上游原料

(3S,5S,6S)-3-[(1S,5R)-5-(tert-butyldiphenylsilyloxy)-1-(methoxymethoxy)hexyl]-5,6-bis-(4-methoxyphenyl)-[1,4]-dioxan-2-one 1,2-di(p-methoxyphenyl)ethylene

下游产品

(3S,7S,8R,9R)-8,9-dihydroxy-7-(methoxymethoxy)-3-methyl-3,4,5,6,7,8,9,10-octahydro-1H-2-benzoxacyclotetradecin-1-one (3S,7S,8S,9R)-8-hydroxy-7-(methoxymethoxy)-3-methyl-9-[(triethylsilyl)oxy]-3,4,5,6,7,8,9,10-octahydro-1H-2-benzoxacyclotetradecin-1-one (3S,7S,9R)-7-(methoxymethoxy)-3-methyl-9-[(triethylsilyl)oxy]-4,5,6,7,9,10-hexahydro-1H-2-benzoxacyclotetradecin-1,8(3H)-dione