百科

(3aR,5R,6R,6aR)-6-Allyloxy-6-(2-benzyloxy-ethyl)-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

(3aR,5R,6R,6aR)-6-Allyloxy-6-(2-benzyloxy-ethyl)-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

CAS号：921202-70-2

英文名：(3aR,5R,6R,6aR)-6-Allyloxy-6-(2-benzyloxy-ethyl)-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

分子式：C21H28O5

分子量：360.444

合成路线

1,2:5,6-di-O-isopropylidene-3-C-(1'-hydroxyethyl)-α-D-allo-1,4-furanose

1,2:5,6-di-O-isopropylidene-3-C-(1'-hydroxyethyl)-α-D-allo-1,4-furanose

(3aR,5R,6R,6aR)-6-Allyloxy-6-(2-benzyloxy-ethyl)-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

(3aR,5R,6R,6aR)-6-Allyloxy-6-(2-benzyloxy-ethyl)-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

(3aR,5R,6R,6aR)-6-Allyloxy-6-(2-benzyloxy-ethyl)-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

(3aR,5R,6R,6aR)-6-Allyloxy-6-(2-benzyloxy-ethyl)-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

(3aR,5R,6R,6aR)-6-Allyloxy-6-(2-benzyloxy-ethyl)-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

(3aR,5R,6R,6aR)-6-Allyloxy-6-(2-benzyloxy-ethyl)-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

3-C-allyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

3-C-allyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

(3aR,5R,6R,6aR)-6-Allyloxy-6-(2-benzyloxy-ethyl)-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

(3aR,5R,6R,6aR)-6-Allyloxy-6-(2-benzyloxy-ethyl)-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

上游原料

3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose 3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose 1,2:5,6-di-O-isopropylidene-3-C-(1'-hydroxyethyl)-α-D-allo-1,4-furanose 3-C-allyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

下游产品

2,2-Dimethyl-propionic acid (1R,2R,3R,5R,6R,12S)-3-(4-acetylamino-2-oxo-2H-pyrimidin-1-yl)-12-methoxy-7-(2-methyl-propane-2-sulfonyl)-4,10-dioxa-7-aza-tricyclo[4.3.3.01,5]dodec-2-yl ester 2,2,2-trichloroethyl (3aR,3bR,6R,7R,7aR,8aR)-6-hydroxy-2,2-dimethylhexahydro-7,3b-(epiminoethano)[1,3]dioxolo[4',5':4,5]furo[3,2-b]pyran-9-carboxylate (1R,4S,5S,9R)-1-((R)-1-Hydroxy-2,2-bis-phenylsulfanyl-ethyl)-4-methoxy-6-(2-methyl-propane-2-sulfonyl)-2-oxa-6-aza-bicyclo[3.3.1]nonan-9-ol (9H-fluoren-9-yl)methyl (3aR,3bR,6R,7R,7aR,8aR)-6-hydroxy-2,2-dimethylhexahydro-7,3b-(epiminoethano)[1,3]dioxolo[4',5':4,5]furo[3,2-b]pyran-9-carboxylate (3aR,3bR,6R,7R,7aR,8aR)-2,2-dimethylhexahydro-7,3b-(epiminoethano)[1,3]dioxolo[4',5':4,5]furo[3,2-b]pyran-6-ol (3aR,3bR,6S,7R,7aR,8aR)-9-(tert-butylsulfonyl)-6-methoxy-2,2-dimethylhexahydro-7,3b-(epiminoethano)[1,3]dioxolo[4',5':4,5]furo[3,2-b]pyran (3aR,3bR,7aR,8aR)-3b-(2-Benzyloxy-ethyl)-2,2-dimethyl-3a,5,7a,8a-tetrahydro-3bH-[1,3]dioxolo[4,5]furo[3,2-b]pyran Toluene-4-sulfonic acid (3aR,3bR,6S,7S,7aR,8aR)-3b-(2-azido-ethyl)-6-hydroxy-2,2-dimethyl-hexahydro-[1,3]dioxolo[4,5]furo[3,2-b]pyran-7-yl ester (3aR,3bR,6S,7S,7aR,8aR)-6-hydroxy-2,2-dimethyl-3b-(2-(tosyloxy)ethyl)hexahydro-5H-[1,3]dioxolo[4',5':4,5]furo[3,2-b]pyran-7-yl 4-methylbenzenesulfonate (9H-fluoren-9-yl)methyl (3aR,3bR,6S,7R,7aR,8aR)-6-hydroxy-2,2-dimethylhexahydro-7,3b-(epiminoethano)[1,3]dioxolo[4',5':4,5]furo[3,2-b]pyran-9-carboxylate (9H-fluoren-9-yl)methyl (3aR,3bR,7S,7aR,8aR)-2,2-dimethyl-6-oxohexahydro-7,3b-(epiminoethano)[1,3]dioxolo[4',5':4,5]furo[3,2-b]pyran-9-carboxylate 2,2,2-trichloroethyl (3aR,3bR,6S,7R,7aR,8aR)-6-hydroxy-2,2-dimethylhexahydro-7,3b-(epiminoethano)[1,3]dioxolo[4',5':4,5]furo[3,2-b]pyran-9-carboxylate 2,2-Dimethyl-propionic acid (1R,2R,3R,5R,6R,12S)-12-methoxy-7-(2-methyl-propane-2-sulfonyl)-3-phenylsulfanyl-4,10-dioxa-7-aza-tricyclo[4.3.3.01,5]dodec-2-yl ester (3aR,3bR,6S,7S,7aR,8aR)-3b-(2-Benzyloxy-ethyl)-2,2-dimethyl-hexahydro-[1,3]dioxolo[4,5]furo[3,2-b]pyran-6,7-diol