百科

6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol

6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol

CAS号：924286-27-1

英文名：6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol

分子式：C27H48O4Si

分子量：464.753

合成路线

(2R,3S)-threo-3-methylbutane-1,2,4-triol

(2R,3S)-threo-3-methylbutane-1,2,4-triol

6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol

6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol

(2S,5S,6R,7S,8Z,10Z,12E)-7-(tert-butyldimethylsilyloxy)-5-(1-ethoxyethyloxy)-2-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-6-methyltetradeca-8,10,12-triene

(2S,5S,6R,7S,8Z,10Z,12E)-7-(tert-butyldimethylsilyloxy)-5-(1-ethoxyethyloxy)-2-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-6-methyltetradeca-8,10,12-triene

6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol

6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol

(2R,3S)-4-(4-methoxybenzyloxy)-3-methylbutane-1,2-diol

(2R,3S)-4-(4-methoxybenzyloxy)-3-methylbutane-1,2-diol

6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol

6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol

(R)-2,2-diethyl-4-[(S)-1-(4-methoxybenzyloxy)propan-2-yl]-1,3-dioxolane

(R)-2,2-diethyl-4-[(S)-1-(4-methoxybenzyloxy)propan-2-yl]-1,3-dioxolane

6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol

6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol

上游原料

(R)-2,2-diethyl-4-[(S)-1-(4-methoxybenzyloxy)propan-2-yl]-1,3-dioxolane (2R,3S)-threo-3-methylbutane-1,2,4-triol (2S,5S,6R,7S,8Z,10Z,12E)-7-(tert-butyldimethylsilyloxy)-5-(1-ethoxyethyloxy)-2-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-6-methyltetradeca-8,10,12-triene (2R,3S)-4-(4-methoxybenzyloxy)-3-methylbutane-1,2-diol

下游产品

dephosphocytostatin (2S,5S,6S,7S,8Z,10Z,12E)-7-(tert-butyldimethylsilyloxy)-6-methyl-2-((2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-tetradeca-8,10,12-trien-5-yl sulfate