百科

(2R,3S,6S)-6-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-2-methyl-3-(triethylsilyloxy)heptanal

(2R,3S,6S)-6-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-2-methyl-3-(triethylsilyloxy)heptanal

CAS号：924286-51-1

英文名：(2R,3S,6S)-6-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-2-methyl-3-(triethylsilyloxy)heptanal

分子式：C21H40O4Si

分子量：384.625

合成路线

(2R,3S,6S)-6-[(2S,3S,6R)-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-1-(4-methoxybenzyloxy)]-2-methylheptan-3-ol

(2R,3S,6S)-6-[(2S,3S,6R)-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-1-(4-methoxybenzyloxy)]-2-methylheptan-3-ol

(2R,3S,6S)-6-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-2-methyl-3-(triethylsilyloxy)heptanal

(2R,3S,6S)-6-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-2-methyl-3-(triethylsilyloxy)heptanal

(2R,5S,6S)-6-[(1S)-2-(tert-butyldiphenylsilyloxy)-1-methylethyl]-5-methyl-2-methoxy-5,6-dihydro-2H-pyran

(2R,5S,6S)-6-[(1S)-2-(tert-butyldiphenylsilyloxy)-1-methylethyl]-5-methyl-2-methoxy-5,6-dihydro-2H-pyran

(2R,3S,6S)-6-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-2-methyl-3-(triethylsilyloxy)heptanal

(2R,3S,6S)-6-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-2-methyl-3-(triethylsilyloxy)heptanal

(2S,3S,6R)-2-[(2S,5S,6R)-5-triethylsilyloxy-7-(4-methoxybenzyloxy)-6-methylheptan-2-yl]-6-methoxy-3-methyl-3,6-dihydro-2H-pyran

(2S,3S,6R)-2-[(2S,5S,6R)-5-triethylsilyloxy-7-(4-methoxybenzyloxy)-6-methylheptan-2-yl]-6-methoxy-3-methyl-3,6-dihydro-2H-pyran

(2R,3S,6S)-6-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-2-methyl-3-(triethylsilyloxy)heptanal

(2R,3S,6S)-6-[(2S,3S,6R)-6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl]-2-methyl-3-(triethylsilyloxy)heptanal

上游原料

(2R,5S,6S)-6-[(1S)-2-(tert-butyldiphenylsilyloxy)-1-methylethyl]-5-methyl-2-methoxy-5,6-dihydro-2H-pyran (2S,3S,6R)-2-[(2S,5S,6R)-5-triethylsilyloxy-7-(4-methoxybenzyloxy)-6-methylheptan-2-yl]-6-methoxy-3-methyl-3,6-dihydro-2H-pyran (2R,3S,6S)-6-[(2S,3S,6R)-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-1-(4-methoxybenzyloxy)]-2-methylheptan-3-ol

下游产品

6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-2H-pyran-2-ol 6-[6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-1,5-dimethyl-trideca-7,9,11-trienyl]-5-methyl-5,6-dihydro-pyran-2-one