百科

3-[(2S,4aS,5aR,8S,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol

3-[(2S,4aS,5aR,8S,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol

CAS号：924656-44-0

英文名：3-[(2S,4aS,5aR,8S,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol

分子式：C29H48O7Si

分子量：536.773

合成路线

(1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-7-methyl-2,6,11-trioxa-tricyclo[8.5.0.03,7]pentadecan-5-one

(1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-7-methyl-2,6,11-trioxa-tricyclo[8.5.0.03,7]pentadecan-5-one

3-[(2S,4aS,5aR,8S,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol

3-[(2S,4aS,5aR,8S,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol

3-[(2R,3S,5aR,7S,8R,10aS)-8-Benzyloxy-7-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-3-methyl-decahydro-1,6-dioxa-heptalen-2-yl]-propan-1-ol

3-[(2R,3S,5aR,7S,8R,10aS)-8-Benzyloxy-7-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-3-methyl-decahydro-1,6-dioxa-heptalen-2-yl]-propan-1-ol

3-[(2S,4aS,5aR,8S,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol

3-[(2S,4aS,5aR,8S,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol

2-[(2R,3S,5aR,7S,8R,10aS)-8-Benzyloxy-7-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-3-methyl-decahydro-1,6-dioxa-heptalen-2-yl]-ethanol

2-[(2R,3S,5aR,7S,8R,10aS)-8-Benzyloxy-7-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-3-methyl-decahydro-1,6-dioxa-heptalen-2-yl]-ethanol

3-[(2S,4aS,5aR,8S,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol

3-[(2S,4aS,5aR,8S,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol

((2R,4aR,6S,7R,9aS)-7-Benzyloxy-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-yl)-methanol

((2R,4aR,6S,7R,9aS)-7-Benzyloxy-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-yl)-methanol

3-[(2S,4aS,5aR,8S,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol

3-[(2S,4aS,5aR,8S,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol

上游原料

(1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-7-methyl-2,6,11-trioxa-tricyclo[8.5.0.03,7]pentadecan-5-one 3-[(2R,3S,5aR,7S,8R,10aS)-8-Benzyloxy-7-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-3-methyl-decahydro-1,6-dioxa-heptalen-2-yl]-propan-1-ol 2-[(2R,3S,5aR,7S,8R,10aS)-8-Benzyloxy-7-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-3-methyl-decahydro-1,6-dioxa-heptalen-2-yl]-ethanol ((2R,4aR,6S,7R,9aS)-7-Benzyloxy-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-yl)-methanol

下游产品