百科

(5R,6R)-5-(benzyloxymethyl)-2,2,3,3,6,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

(5R,6R)-5-(benzyloxymethyl)-2,2,3,3,6,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

CAS号：927396-39-2

英文名：(5R,6R)-5-(benzyloxymethyl)-2,2,3,3,6,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

分子式：C24H46O3Si2

分子量：438.791

合成路线

(5R,6R,E)-methyl 7-(benzyloxy)-6-(tert-butyldimethylsilyloxy)-5-methylhept-3-enoate

(5R,6R,E)-methyl 7-(benzyloxy)-6-(tert-butyldimethylsilyloxy)-5-methylhept-3-enoate

(5R,6R)-5-(benzyloxymethyl)-2,2,3,3,6,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

(5R,6R)-5-(benzyloxymethyl)-2,2,3,3,6,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

Oxiranemethanol, 3-[(phenylmethoxy)methyl]-, (2S-trans)-

Oxiranemethanol, 3-[(phenylmethoxy)methyl]-, (2S-trans)-

(5R,6R)-5-(benzyloxymethyl)-2,2,3,3,6,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

(5R,6R)-5-(benzyloxymethyl)-2,2,3,3,6,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

上游原料

(5R,6R,E)-methyl 7-(benzyloxy)-6-(tert-butyldimethylsilyloxy)-5-methylhept-3-enoate

下游产品

(2R,3R)-4-azido-3-(tert-butyldimethylsilyloxy)-2-methylbutan-1-ol (5R,6R)-5-(azidomethyl)-2,2,3,3,6,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane (2S,3R)-4-amino-3-(tert-butyldimethylsilyloxy)-2-methylbutyric acid triisopropylsilyl ester (2S,3R)-4-azido-3-(tert-butyldimethylsilyloxy)-2-methylbutyric acid triisopropylsilyl ester (2S,3R)-4-azido-3-(tert-butyldimethylsilyloxy)-2-methylbutyric acid (2S,3R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-4-{2-[(2S,3S,6R)-3-methyl-6-((E)-2-oxopent-3-enyl)tetrahydro-pyran-2-yl]-acetylamino}-butyric acid triisopropylsilyl ester (2S,3R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-4-{2-[(2S,3S,6R)-3-methyl-6-((E)-2-oxopent-3-enyl)tetrahydro-pyran-2-yl]-acetylamino}-butyric acid 3-(tert-butyl-dimethyl-silanyloxy)-N-(3-{8-[6-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hept-4-enyl]-3-methyl-1,7-dioxa-spiro[5.5]undec-2-yl}-propyl)-2-methyl-4-{2-[3-methyl-6-(2-oxopent-3-enyl)tetrahydro-pyran-2-yl]-acetylamino}-butyramide