百科

(2R,3R,4R,5R)-4-benzoyloxy-3-benzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine

(2R,3R,4R,5R)-4-benzoyloxy-3-benzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine

CAS号：927809-69-6

英文名：(2R,3R,4R,5R)-4-benzoyloxy-3-benzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine

分子式：C44H47NO7Si

分子量：729.932

合成路线

4-O-benzoyl-3-O-benzyl-5-deoxy-5-iodo-1,2-O-isopropylidene-α-L-sorbopyranose

4-O-benzoyl-3-O-benzyl-5-deoxy-5-iodo-1,2-O-isopropylidene-α-L-sorbopyranose

(2R,3R,4R,5R)-4-benzoyloxy-3-benzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine

(2R,3R,4R,5R)-4-benzoyloxy-3-benzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine

5-azido-4-O-benzoyl-3-O-benzyl-1-O-tert-butyldiphenylsilyl-5-deoxy-β-D-fructopyranose

5-azido-4-O-benzoyl-3-O-benzyl-1-O-tert-butyldiphenylsilyl-5-deoxy-β-D-fructopyranose

(2R,3R,4R,5R)-4-benzoyloxy-3-benzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine

(2R,3R,4R,5R)-4-benzoyloxy-3-benzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine

10-(benzyloxy)-2,2-dimethyl-1,3,6-trioxaspiro(4,5)decane-8,9-diol

10-(benzyloxy)-2,2-dimethyl-1,3,6-trioxaspiro(4,5)decane-8,9-diol

(2R,3R,4R,5R)-4-benzoyloxy-3-benzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine

(2R,3R,4R,5R)-4-benzoyloxy-3-benzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine

上游原料

4-O-benzoyl-3-O-benzyl-5-deoxy-5-iodo-1,2-O-isopropylidene-α-L-sorbopyranose 5-azido-4-O-benzoyl-3-O-benzyl-1-O-tert-butyldiphenylsilyl-5-deoxy-β-D-fructopyranose 10-(benzyloxy)-2,2-dimethyl-1,3,6-trioxaspiro(4,5)decane-8,9-diol

下游产品

benzyl (2S,3R,4R,5R)-3-(benzoyloxy)-4-(benzyloxy)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-2-formylpyrrolidine-1-carboxylate