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(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

CAS号：932739-33-8

英文名：(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

分子式：C17H24O3

分子量：276.371

合成路线

(4S,5S,6R,7R)-4-benzoyloxy-6,7-isopropylidenedioxy-5-methyl-7-phenylhept-1-ene

(4S,5S,6R,7R)-4-benzoyloxy-6,7-isopropylidenedioxy-5-methyl-7-phenylhept-1-ene

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

1315500-59-4

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(4S,5S,6S,7R)-6-tert-butyldiphenylsilyloxy-7,8-cyclohexylidenedioxy-5-methyloct-1-en-4-ol

(4S,5S,6S,7R)-6-tert-butyldiphenylsilyloxy-7,8-cyclohexylidenedioxy-5-methyloct-1-en-4-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2R,3R,4S,5S)-5-benzoyloxy-3-tert-butyldiphenylsilyloxy-4-methyloct-7-ene-1,2-diol

(2R,3R,4S,5S)-5-benzoyloxy-3-tert-butyldiphenylsilyloxy-4-methyloct-7-ene-1,2-diol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2R,3S,4S)-4-benzoyloxy-2-tert-butyldiphenylsilyloxy-3-methylhept-6-enal

(2R,3S,4S)-4-benzoyloxy-2-tert-butyldiphenylsilyloxy-3-methylhept-6-enal

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(3S,4S)-1-(benzyloxy)-4-((4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl)pentan-3-yl acetate

(3S,4S)-1-(benzyloxy)-4-((4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl)pentan-3-yl acetate

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(3S,4S)-1-(benzyloxy)-4-((4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl)pentan-3-ol

(3S,4S)-1-(benzyloxy)-4-((4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl)pentan-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3R,4S,6S)-2-(2-(benzyloxy)ethyl)-6-(hydroxymethyl)-3-methyltetrahydro-2H-pyran-4-ol

(2S,3R,4S,6S)-2-(2-(benzyloxy)ethyl)-6-(hydroxymethyl)-3-methyltetrahydro-2H-pyran-4-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

((2S,4S,5R,6S)-6-(2-(benzyloxy)ethyl)-4-hydroxy-5-methyltetrahydro-2H-pyran-2-yl)methyl-4-methylbenzenesulfonate

((2S,4S,5R,6S)-6-(2-(benzyloxy)ethyl)-4-hydroxy-5-methyltetrahydro-2H-pyran-2-yl)methyl-4-methylbenzenesulfonate

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(3S,4S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pentane-1,3-diol

(3S,4S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pentane-1,3-diol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

(2S,3S)-2-[(4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]hex-5-en-3-ol

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上游原料

(3S,4S)-1-(benzyloxy)-4-((4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl)pentan-3-yl acetate (2S,3R,4S,6S)-2-(2-(benzyloxy)ethyl)-6-(hydroxymethyl)-3-methyltetrahydro-2H-pyran-4-ol (3S,4S)-1-(benzyloxy)-4-((4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl)pentan-3-ol (4S,5S,6R,7R)-4-benzoyloxy-6,7-isopropylidenedioxy-5-methyl-7-phenylhept-1-ene (4S,5S,6S,7R)-4-benzoyloxy-6-tert-butyldiphenylsilyloxy-7,8-cyclohexylidenedioxy-5-methyloct-1-ene (2R,3S,4S)-4-benzoyloxy-2-tert-butyldiphenylsilyloxy-3-methylhept-6-enal (4S,5S,6S,7R)-6-tert-butyldiphenylsilyloxy-7,8-cyclohexylidenedioxy-5-methyloct-1-en-4-ol (2R,3R,4S,5S)-5-benzoyloxy-3-tert-butyldiphenylsilyloxy-4-methyloct-7-ene-1,2-diol (3S,4R,5R,6R)-1-(benzyloxy)-5,6-dihydroxy-4-methyl-6-phenylhexan-3-yl acetate (2R,3R,4R,5S)-5-benzoyloxy-1,2-cyclohexylidenedioxy-4-methyloct-7-en-3-ol (3S,4S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pentane-1,3-diol (2S,3S,4R)-2-(2-(benzyloxy)ethyl)-4-(methoxymethoxy)-3,6-dimethyl-3,4-dihydro-2H-pyran (3S,4S,5R,6R)-1-(benzyloxy)-6-hydroxy-5-(methoxymethoxy)-4-methyl-6-phenylhexan-3-yl acetate ((2S,4S,5S,6S)-6-(2-(benzyloxy)ethyl)-4-(methoxymethoxy)-5-methyltetrahydro-2H-pyran-2-yl)methyl 4-methylbenzenesulfonate (2S,3S,4S,6S)-2-(2-(benzyloxy)ethyl)-6-(iodomethyl)-4-(methoxymethoxy)-3-methyltetrahydro-2H-pyran ((2S,4S,5R,6S)-6-(2-(benzyloxy)ethyl)-4-hydroxy-5-methyltetrahydro-2H-pyran-2-yl)methyl-4-methylbenzenesulfonate

下游产品

(3S,10R,16S,E)-16-((2R,3R,4R)-3,4-dihydroxy-4-phenylbutan-2-yl)-3-isobutyl-10-(4-methoxybenzyl)-1,4-dioxa-8,11-diazacyclohexadec-13-ene-2,5,9,12-tetraone (2S,3S)-2-((4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl)hex-5-en-3-yl (S)-2-((3-((R)-2-acrylamido-3-(4-methoxyphenyl)propanamido)propanoyl)oxy)-4-methylpentanoate (3S,10R,16S,E)-16-((S)-1-((4R,5R)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl)ethyl)-3-isobutyl-10-(4-methoxybenzyl)-1,4-dioxa-8,11-diazacyclohexadec-13-ene-2,5,9,12-tetraone