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(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

CAS号：935248-67-2

英文名：(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

分子式：C13H20O5

分子量：256.295

合成路线

1334630-98-6

(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

1334630-61-3

(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

methyl (5S,7R,8R)-7,8-bis((tert-butyldimethylsilyl)oxy)-5-hydroxynon-2-ynoate

methyl (5S,7R,8R)-7,8-bis((tert-butyldimethylsilyl)oxy)-5-hydroxynon-2-ynoate

(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

L-talonic acid γ-lactone

L-talonic acid γ-lactone

(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

3,6-dideoxy-D-xylo-hexitol

3,6-dideoxy-D-xylo-hexitol

(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

(S)-5-hydroxy-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-2-ynoic acid methyl ester

上游原料

3,6-dideoxy-D-xylo-hexitol L-talonic acid γ-lactone methyl (5S,7R,8R)-7,8-bis((tert-butyldimethylsilyl)oxy)-5-hydroxynon-2-ynoate

下游产品

[3-acetoxy-2-(1,1-dimethyl-2-oxo-ethyl)-2-methoxy-6-(2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-tetrahydro-pyran-4-ylidene]-acetic acid methyl ester methyl (E)-2-((2S,3S,6S)-3-acetoxy-6-((2R,3R)-2,3-dihydroxybutyl)-2-hydroxy-2-((E)-2-methylnona-3,8-dien-2-yl)tetrahydro-4H-pyran-4-ylidene)acetate E-7-(tert-butyl-dimethyl-silanyloxy)-3-[2-hydroxy-3-(2,2,5-trimethyl-[1,3]dioxolan-4-yl)-propyl]-6,6-dimethyl-hept-2-en-4-ynoic acid methyl ester [3-acetoxy-2-(1,1-dimethyl-octa-2,7-dienyl)-2-methoxy-6-(2,2,5-trimetyl-[1,3]dioxolan-4-ylmethyl)-tetrahydro-pyran-4-ylidene]-acetic acid methyl ester methyl (E)-2-((2S,6S)-2-(1-((tert-butyldimethylsilyl)oxy)-2-methylpropan-2-yl)-2-methoxy-3-oxo-6-(((4R,5R)-2,2,5-trimethyl-1,3-dioxolan-4-yl)methyl)tetrahydro-4H-pyran-4-ylidene)acetate [3-acetoxy-2-(2-hydroxy-1,1-dimethyl-ethyl)-2-methoxy-6-(2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-tetrahydro-pyran-4-ylidene]-acetic acid methyl ester