百科

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

CAS号：936573-15-8

英文名：(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

分子式：C34H48O6

分子量：552.741

合成路线

2,2-Dimethyl-propionic acid (4R,5S,6S)-6-((S)-2-cyano-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-ylmethyl ester

2,2-Dimethyl-propionic acid (4R,5S,6S)-6-((S)-2-cyano-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-ylmethyl ester

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

2,2-Dimethyl-propionic acid (4R,5S,6S)-2,2,5-trimethyl-6-[(S)-1-methyl-2-(toluene-4-sulfonyloxy)-ethyl]-[1,3]dioxan-4-ylmethyl ester

2,2-Dimethyl-propionic acid (4R,5S,6S)-2,2,5-trimethyl-6-[(S)-1-methyl-2-(toluene-4-sulfonyloxy)-ethyl]-[1,3]dioxan-4-ylmethyl ester

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4R,5S,6S)-3,5-Bis-benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-4,6-dimethyl-heptan-1-ol

(3S,4R,5S,6S)-3,5-Bis-benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-4,6-dimethyl-heptan-1-ol

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(2R,3R,4S,5S)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-3,5-dimethyl-hexane-1,2-diol

(2R,3R,4S,5S)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-3,5-dimethyl-hexane-1,2-diol

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

((2S,3S,4R,5S)-3,5-Bis-benzyloxy-7-methoxymethoxy-2,4-dimethyl-heptyloxy)-tert-butyl-diphenyl-silane

((2S,3S,4R,5S)-3,5-Bis-benzyloxy-7-methoxymethoxy-2,4-dimethyl-heptyloxy)-tert-butyl-diphenyl-silane

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(2S,3S,4R,5S)-3,5-Bis-benzyloxy-7-methoxymethoxy-2,4-dimethyl-heptan-1-ol

(2S,3S,4R,5S)-3,5-Bis-benzyloxy-7-methoxymethoxy-2,4-dimethyl-heptan-1-ol

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3S,4S,5R,6S)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

上游原料

2,2-Dimethyl-propionic acid (4R,5S,6S)-6-((S)-2-cyano-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-ylmethyl ester 2,2-Dimethyl-propionic acid (4R,5S,6S)-2,2,5-trimethyl-6-[(S)-1-methyl-2-(toluene-4-sulfonyloxy)-ethyl]-[1,3]dioxan-4-ylmethyl ester (2S,3S,4R,5S)-3,5-Bis-benzyloxy-7-methoxymethoxy-2,4-dimethyl-heptan-1-ol ((2S,3S,4R,5S)-3,5-Bis-benzyloxy-7-methoxymethoxy-2,4-dimethyl-heptyloxy)-tert-butyl-diphenyl-silane (3S,4R,5S,6S)-3,5-Bis-benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-4,6-dimethyl-heptan-1-ol (2R,3R,4S,5S)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-3,5-dimethyl-hexane-1,2-diol

下游产品

(3S,4R,5S,6S)-8-((3S,4R,5S,6S)-4,6-Dimethyl-2,8-dioxa-bicyclo[3.2.1]oct-3-yl)-4,6-dimethyl-octane-1,3,5-triol Acetic acid (1S,2R,3S,4S)-3-acetoxy-6-((3S,4R,5S,6S)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]oct-3-yl)-2,4-dimethyl-1-(2-trityloxy-ethyl)-hexyl ester