百科

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

CAS号：936573-16-9

英文名：(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

分子式：C34H48O6

分子量：552.741

合成路线

2,2-Dimethyl-propionic acid (4R,5S,6S)-6-((S)-2-cyano-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-ylmethyl ester

2,2-Dimethyl-propionic acid (4R,5S,6S)-6-((S)-2-cyano-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-ylmethyl ester

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(2R,3R,4S,5R)-3,5-Bis-benzyloxy-7-methoxymethoxy-2,4-dimethyl-heptan-1-ol

(2R,3R,4S,5R)-3,5-Bis-benzyloxy-7-methoxymethoxy-2,4-dimethyl-heptan-1-ol

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

2,2-Dimethyl-propionic acid (4R,5S,6S)-2,2,5-trimethyl-6-[(S)-1-methyl-2-(toluene-4-sulfonyloxy)-ethyl]-[1,3]dioxan-4-ylmethyl ester

2,2-Dimethyl-propionic acid (4R,5S,6S)-2,2,5-trimethyl-6-[(S)-1-methyl-2-(toluene-4-sulfonyloxy)-ethyl]-[1,3]dioxan-4-ylmethyl ester

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

ethyl (2E,4S,5R)-5,6-isopropylidenedioxy-4-methyl-2-hexenoate

ethyl (2E,4S,5R)-5,6-isopropylidenedioxy-4-methyl-2-hexenoate

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

((2R,3R,4R)-3-Benzyloxy-2-methyl-4-(S)-oxiranyl-pentyloxy)-tert-butyl-diphenyl-silane

((2R,3R,4R)-3-Benzyloxy-2-methyl-4-(S)-oxiranyl-pentyloxy)-tert-butyl-diphenyl-silane

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

((2R,3R,4S,5R)-3,5-Bis-benzyloxy-6-[1,3]dithian-2-yl-2,4-dimethyl-hexyloxy)-tert-butyl-diphenyl-silane

((2R,3R,4S,5R)-3,5-Bis-benzyloxy-6-[1,3]dithian-2-yl-2,4-dimethyl-hexyloxy)-tert-butyl-diphenyl-silane

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

(3S,4S,5S,6S)-3-((Z)-(3R,4R,5S,6R)-4,6-Bis-benzyloxy-8-methoxymethoxy-3,5-dimethyl-oct-1-enyl)-4,6-dimethyl-2,8-dioxa-bicyclo[3.2.1]octane

上游原料

2,2-Dimethyl-propionic acid (4R,5S,6S)-6-((S)-2-cyano-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-ylmethyl ester 2,2-Dimethyl-propionic acid (4R,5S,6S)-2,2,5-trimethyl-6-[(S)-1-methyl-2-(toluene-4-sulfonyloxy)-ethyl]-[1,3]dioxan-4-ylmethyl ester ((2R,3R,4R)-3-Benzyloxy-2-methyl-4-(S)-oxiranyl-pentyloxy)-tert-butyl-diphenyl-silane ((2R,3R,4S,5R)-3,5-Bis-benzyloxy-6-[1,3]dithian-2-yl-2,4-dimethyl-hexyloxy)-tert-butyl-diphenyl-silane (2R,3R,4S,5R)-3,5-Bis-benzyloxy-7-methoxymethoxy-2,4-dimethyl-heptan-1-ol ethyl (2E,4S,5R)-5,6-isopropylidenedioxy-4-methyl-2-hexenoate

下游产品

(3R,4S,5R,6R)-8-((3S,4R,5S,6S)-4,6-Dimethyl-2,8-dioxa-bicyclo[3.2.1]oct-3-yl)-1-methoxymethoxy-4,6-dimethyl-octane-3,5-diol