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2-((4aS,5S,7S,8aR)-7-(hydroxymethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol

2-((4aS,5S,7S,8aR)-7-(hydroxymethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol

CAS号：936642-32-9

英文名：2-((4aS,5S,7S,8aR)-7-(hydroxymethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol

分子式：C13H24O5

分子量：260.327

合成路线

(2R,3R)-4-(benzyloxy)-3-(((S)-5-(benzyloxy)-2-methylpent-1-en-3-yl)oxy)-2-hydroxybutyl 4-methylbenzenesulfonate

(2R,3R)-4-(benzyloxy)-3-(((S)-5-(benzyloxy)-2-methylpent-1-en-3-yl)oxy)-2-hydroxybutyl 4-methylbenzenesulfonate

2-((4aS,5S,7S,8aR)-7-(hydroxymethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol

2-((4aS,5S,7S,8aR)-7-(hydroxymethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol

tert-butyl(((4aS,5S,7S,8aR)-5-(2-((tert-butyldimethylsilyl)oxy)ethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-7-yl)methoxy)dimethylsilane

tert-butyl(((4aS,5S,7S,8aR)-5-(2-((tert-butyldimethylsilyl)oxy)ethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-7-yl)methoxy)dimethylsilane

2-((4aS,5S,7S,8aR)-7-(hydroxymethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol

2-((4aS,5S,7S,8aR)-7-(hydroxymethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol

((4aS,5S,7S,8aR)-5-(2-((tert-butyldimethylsilyl)oxy)ethyl)-2,2,4a-trimethylhexahydropyrano[4,3-d][1,3]dioxin-7-yl)-methanol

((4aS,5S,7S,8aR)-5-(2-((tert-butyldimethylsilyl)oxy)ethyl)-2,2,4a-trimethylhexahydropyrano[4,3-d][1,3]dioxin-7-yl)-methanol

(3aS,4S,6S)-4-(2-(benzyloxy)ethyl)-6-((benzyloxy)methyl)-3a-methyl-3a,4,6,7-tetrahydro-3H-pyrano[4,3-c]isoxazole

(3aS,4S,6S)-4-(2-(benzyloxy)ethyl)-6-((benzyloxy)methyl)-3a-methyl-3a,4,6,7-tetrahydro-3H-pyrano[4,3-c]isoxazole

2-((4aS,5S,7S,8aR)-7-(hydroxymethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol

2-((4aS,5S,7S,8aR)-7-(hydroxymethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol

(2S,3R,4R,6S)-2-(2-(benzyloxy)ethyl)-6-((benzyloxy)methyl)-3-(hydroxymethyl)-3-methyltetrahydro-2H-pyran-4-ol

(2S,3R,4R,6S)-2-(2-(benzyloxy)ethyl)-6-((benzyloxy)methyl)-3-(hydroxymethyl)-3-methyltetrahydro-2H-pyran-4-ol

2-((4aS,5S,7S,8aR)-7-(hydroxymethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol

2-((4aS,5S,7S,8aR)-7-(hydroxymethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol

上游原料

tert-butyl(((4aS,5S,7S,8aR)-5-(2-((tert-butyldimethylsilyl)oxy)ethyl)-2,2,4a-trimethyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-7-yl)methoxy)dimethylsilane (2R,3R)-4-(benzyloxy)-3-(((S)-5-(benzyloxy)-2-methylpent-1-en-3-yl)oxy)-2-hydroxybutyl 4-methylbenzenesulfonate (2S,3R,4R,6S)-2-(2-(benzyloxy)ethyl)-6-((benzyloxy)methyl)-3-(hydroxymethyl)-3-methyltetrahydro-2H-pyran-4-ol (3aS,4S,6S)-4-(2-(benzyloxy)ethyl)-6-((benzyloxy)methyl)-3a-methyl-3a,4,6,7-tetrahydro-3H-pyrano[4,3-c]isoxazole

下游产品

2-((4aS,5S,7S,8aR)-2,2,4a-trimethyl-7-((E)-4-((1-phenyl-1H-tetrazol-5-yl)sulfonyl)but-1-en-1-yl)hexahydropyrano[4,3-d]-[1,3]dioxin-5-yl)ethanol ((4aS,5S,7S,8aR)-5-(2-((tert-butyldimethylsilyl)oxy)ethyl)-2,2,4a-trimethylhexahydropyrano[4,3-d][1,3]dioxin-7-yl)-methanol tert-butyldimethyl(2-((4aS,5S,7S,8aR)-2,2,4a-trimethyl-7-vinyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethoxy)silane 2-((4aS,5S,7S,8aR)-2,2,4a-trimethyl-7-vinyltetrahydro-4H,5H-pyrano[4,3-d][1,3]dioxin-5-yl)ethan-1-ol