百科

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

CAS号：936946-38-2

英文名：(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

分子式：C30H49NO5Si

分子量：531.799

合成路线

(2S,4R,5S,6S,E)-1-((S)-4-benzyl-2-oxooxazolidin-3-yl)-5-((tert-butyldimethylsilyl)oxy)-2,4,6,8-tetramethyldec-8-ene-1,3-dione

(2S,4R,5S,6S,E)-1-((S)-4-benzyl-2-oxooxazolidin-3-yl)-5-((tert-butyldimethylsilyl)oxy)-2,4,6,8-tetramethyldec-8-ene-1,3-dione

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'R,3'S,4R,4'S,6E)-3-[(3-hydroxy-2,4,6-trimethyl-1-oxooct-6-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'R,3'S,4R,4'S,6E)-3-[(3-hydroxy-2,4,6-trimethyl-1-oxooct-6-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2R)-(E)-2,4-dimethyl-4-hexenal

(2R)-(E)-2,4-dimethyl-4-hexenal

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'R,3'S,4'S,6E,4R)-3-[(3-[tert-butyldimethylsilyloxy]-2,4,6-trimethyl-1-oxo-oct-6-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'R,3'S,4'S,6E,4R)-3-[(3-[tert-butyldimethylsilyloxy]-2,4,6-trimethyl-1-oxo-oct-6-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2S,4E)-2,4-dimethylhex-4-en-1-ol

(2S,4E)-2,4-dimethylhex-4-en-1-ol

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2S,4E)-2,4-dimethyl-4-hexenal

(2S,4E)-2,4-dimethyl-4-hexenal

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

(2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone

上游原料

(2S,4R,5S,6S,E)-1-((S)-4-benzyl-2-oxooxazolidin-3-yl)-5-((tert-butyldimethylsilyl)oxy)-2,4,6,8-tetramethyldec-8-ene-1,3-dione (2'R,3'S,4'S,6E,4R)-3-[(3-[tert-butyldimethylsilyloxy]-2,4,6-trimethyl-1-oxo-oct-6-enyl)-4-(phenylmethyl)]-2-oxazolidinone (2S,4E)-2,4-dimethylhex-4-en-1-ol (2R)-(E)-2,4-dimethyl-4-hexenal (2S,4E)-2,4-dimethyl-4-hexenal (2'R,3'S,4R,4'S,6E)-3-[(3-hydroxy-2,4,6-trimethyl-1-oxooct-6-enyl)-4-(phenylmethyl)]-2-oxazolidinone

下游产品

(S)-4-benzyl-3-((2S,3R,4R,5S,6S,E)-3,5-dihydroxy-2,4,6,8-tetramethyldec-8-enoyl)oxazolidin-2-one