百科

(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

CAS号：938455-50-6

英文名：(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

分子式：C49H60O9

分子量：792.995

合成路线

938455-96-0

(S)-3-((2R,4aR,6S,7R,8aS)-7-(benzyloxy)-4a-methyl-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-6-yl)butan-1-ol

938455-50-6

(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

938455-38-0

(2R,3S,5R,6S)-5-(benzyloxy)-6-((S)-4-(benzyloxy)butan-2-yl)-2-(hydroxymethyl)-2-methyltetrahydro-2H-pyran-3-ol

938455-50-6

(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

938455-98-2

((2R,3S,5R,6S)-5-(benzyloxy)-6-((S)-4-(benzyloxy)butan-2-yl)-3-((tert-butyldimethylsilyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)methanol

938455-50-6

(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

938455-34-6

(2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyl-2-(prop-2-yn-1-yl)tetrahydro-2H-pyran

938455-50-6

(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

938455-41-5

1-((2R,3S,5R,6S)-5-(benzyloxy)-6-((S)-4-(benzyloxy)butan-2-yl)-3-((tert-butyldimethylsilyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)-4-((2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)but-2-yn-1-ol

938455-50-6

(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

938455-42-6

1-((2S,3S,5R,6S)-5-(benzyloxy)-6-((S)-4-(benzyloxy)butan-2-yl)-3-((tert-butyldimethylsilyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)-4-((2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)but-2-yn-1-one

938455-50-6

(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

938455-45-9

(4aS,6S,7R,8aS)-7-(benzyloxy)-2-(((2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)methyl)-6-((S)-4-(benzyloxy)butan-2-yl)-4a-methyl-6,7,8,8a-tetrahydropyrano[3,2-b]pyran-4(4aH)-one

938455-50-6

(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

938455-46-0

(4S,4aR,6S,7R,8aS)-7-(benzyloxy)-2-(((2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)methyl)-6-((S)-4-(benzyloxy)butan-2-yl)-4a-methyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-b]pyran-4-ol

938455-50-6

(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

938455-47-1

(2R,3S,4S,4aR,6S,7R,8aS)-7-(benzyloxy)-2-(((2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)methyl)-6-((S)-4-(benzyloxy)butan-2-yl)-4a-methyloctahydropyrano[3,2-b]pyran-3,4-diol

938455-50-6

(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

938455-36-8

methyl (E)-3-((2R,4aR,6S,7R,8aS)-7-(benzyloxy)-4a-methyl-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-6-yl)acrylate

938455-50-6

(2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol

上游原料

下游产品

(S)-3-((4aR,5aS,6aR,7aS,9R,10S,11aS,12S,12aR,13aR,14aS)-9-hydroxy-2,2,5a,11a-tetramethyl-12-((triisopropylsilyl)oxy)tetradecahydro-4H-pyrano[2''',3''':5'',6'']pyrano[2'',3'':5',6']pyrano[2',3':5,6]pyrano[3,2-d][1,3]dioxin-10-yl)butyl pivalate (2S,3R,4aS,5aR,6aS,8R,9S,10aR,11aR,12S,12aS)-9,12-bis(benzyloxy)-8-((benzyloxy)methyl)-2-((S)-but-3-en-2-yl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-3-ol (((4aR,5aS,6aR,7aS,9R,10S,11aS,12S,12aR,13aR,14aS)-10-((S)-but-3-en-2-yl)-9-((4-methoxybenzyl)oxy)-2,2,5a,11a-tetramethyltetradecahydro-4H-pyrano[2''',3''':5'',6'']pyrano[2'',3'':5',6']pyrano[2',3':5,6]pyrano[3,2-d][1,3]dioxin-12-yl)oxy)triisopropylsilane (2R,3S,4aR,5aR,6S,6aS,8S,9R,10aS,11aR,12aS)-3,6-bis(benzyloxy)-2-((benzyloxy)methyl)-8-((S)-but-3-en-2-yl)-9-((4-methoxybenzyl)oxy)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran (4aR,5aS,6aR,7aS,9R,10S,11aR,12S,12aS,13aR,14aS)-10-((S)-but-3-en-2-yl)-9-((4-methoxybenzyl)oxy)-2,2,5a,11a-tetramethyltetradecahydro-4H-pyrano[2''',3''':5'',6'']pyrano[2'',3'':5',6']pyrano[2',3':5,6]pyrano[3,2-d][1,3]dioxin-12-ol (4aR,5aS,6aR,7aS,9R,10S,11aS,12S,12aR,13aR,14aS)-10-((S)-4-hydroxybutan-2-yl)-2,2,5a,11a-tetramethyl-12-((triisopropylsilyl)oxy)tetradecahydro-4H-pyrano[2''',3''':5'',6'']pyrano[2'',3'':5',6']pyrano[2',3':5,6]pyrano[3,2-d][1,3]dioxin-9-ol