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(4aR,5aS,6aR,7aS,9R,10S,11aS,12S,12aR,13aR,14aS)-10-((S)-4-hydroxybutan-2-yl)-2,2,5a,11a-tetramethyl-12-((triisopropylsilyl)oxy)tetradecahydro-4H-pyrano[2''',3''':5'',6'']pyrano[2'',3'':5',6']pyrano[2',3':5,6]pyrano[3,2-d][1,3]dioxin-9-ol

(4aR,5aS,6aR,7aS,9R,10S,11aS,12S,12aR,13aR,14aS)-10-((S)-4-hydroxybutan-2-yl)-2,2,5a,11a-tetramethyl-12-((triisopropylsilyl)oxy)tetradecahydro-4H-pyrano[2''',3''':5'',6'']pyrano[2'',3'':5',6']pyrano[2',3':5,6]pyrano[3,2-d][1,3]dioxin-9-ol

CAS号:938455-52-8
英文名:(4aR,5aS,6aR,7aS,9R,10S,11aS,12S,12aR,13aR,14aS)-10-((S)-4-hydroxybutan-2-yl)-2,2,5a,11a-tetramethyl-12-((triisopropylsilyl)oxy)tetradecahydro-4H-pyrano[2''',3''':5'',6'']pyrano[2'',3'':5',6']pyrano[2',3':5,6]pyrano[3,2-d][1,3]dioxin-9-ol
分子式:C33H60O9Si
分子量:628.91
上游原料
(2R,3S,5R,6S)-2-(hydroxymethyl)-5-((4-methoxybenzyl)oxy)-6-methyl-6-vinyltetrahydro-2H-pyran-3-ol (2R,4aR,6S,7R,8aS)-6-Methyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol (S)-3-((2R,4aR,6S,7R,8aS)-7-(benzyloxy)-4a-methyl-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-6-yl)butan-1-ol methyl (S)-3-((2R,4aR,6S,7R,8aS)-7-(benzyloxy)-4a-methyl-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-6-yl)butanoate ((2R,3S,5R,6S)-5-(benzyloxy)-6-((S)-4-(benzyloxy)butan-2-yl)-3-((tert-butyldimethylsilyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)methanol methyl (E)-3-((2R,4aR,6S,7R,8aS)-7-(benzyloxy)-4a-methyl-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-6-yl)acrylate (2R,3S,4aR,5aS,6S,6aR,8S,9R,10aS,11aR,12aS)-3,9-bis(benzyloxy)-8-((S)-4-(benzyloxy)butan-2-yl)-2-((benzyloxy)methyl)-6a,12a-dimethyltetradecahydropyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-e]pyran-6-ol 1-((2R,3S,5R,6S)-5-(benzyloxy)-6-((S)-4-(benzyloxy)butan-2-yl)-3-((tert-butyldimethylsilyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)-4-((2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)but-2-yn-1-ol (4S,4aR,6S,7R,8aS)-7-(benzyloxy)-2-(((2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)methyl)-6-((S)-4-(benzyloxy)butan-2-yl)-4a-methyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-b]pyran-4-ol (2R,4aR,6S,7R,8aS)-7-(benzyloxy)-4a-methyl-2-phenyl-6-vinylhexahydropyrano[3,2-d][1,3]dioxine (2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyl-2-(prop-2-yn-1-yl)tetrahydro-2H-pyran 1-((2S,3S,5R,6S)-5-(benzyloxy)-6-((S)-4-(benzyloxy)butan-2-yl)-3-((tert-butyldimethylsilyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)-4-((2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)but-2-yn-1-one (2R,3S,4S,4aR,6S,7R,8aS)-7-(benzyloxy)-2-(((2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)methyl)-6-((S)-4-(benzyloxy)butan-2-yl)-4a-methyloctahydropyrano[3,2-b]pyran-3,4-diol (2R,3S,5R,6S)-5-(benzyloxy)-6-((S)-4-(benzyloxy)butan-2-yl)-2-(hydroxymethyl)-2-methyltetrahydro-2H-pyran-3-ol (2S,3S,5R,6S)-5-(benzyloxy)-6-((S)-4-(benzyloxy)butan-2-yl)-3-((tert-butyldimethylsilyl)oxy)-2-methyltetrahydro-2H-pyran-2-carbaldehyde (2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyl-2-vinyltetrahydro-2H-pyran (2S,5S,6R)-5-(benzyloxy)-2-(((2R,3S,4S,4aR,6S,7R,8aS)-7-(benzyloxy)-6-((S)-4-(benzyloxy)butan-2-yl)-3,4-dihydroxy-4a-methyloctahydropyrano[3,2-b]pyran-2-yl)methyl)-6-((benzyloxy)methyl)-2-methyldihydro-2H-pyran-3(4H)-one (4aS,6S,7R,8aS)-7-(benzyloxy)-2-(((2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)methyl)-6-((S)-4-(benzyloxy)butan-2-yl)-4a-methyl-6,7,8,8a-tetrahydropyrano[3,2-b]pyran-4(4aH)-one 2-((2S,3R,5S,6R)-5-(benzyloxy)-6-((benzyloxy)methyl)-3-((4-methoxybenzyl)oxy)-2-methyltetrahydro-2H-pyran-2-yl)ethan-1-ol