百科

3(R)-methyl-6(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>-2(S)-(3-oxobutyl)cyclohexanone

3(R)-methyl-6(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>-2(S)-(3-oxobutyl)cyclohexanone

CAS号：93913-62-3

英文名：3(R)-methyl-6(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>-2(S)-(3-oxobutyl)cyclohexanone

分子式：C21H30O3

分子量：330.461

合成路线

(2S,3R,6S)-6-((R)-1-(benzyloxy)prop-2-yl)-3-methyl-2-((E)-3-(trimethylsilyl)but-2-en-1-yl)cyclohexanone

(2S,3R,6S)-6-((R)-1-(benzyloxy)prop-2-yl)-3-methyl-2-((E)-3-(trimethylsilyl)but-2-en-1-yl)cyclohexanone

3(R)-methyl-6(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>-2(S)-(3-oxobutyl)cyclohexanone

3(R)-methyl-6(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>-2(S)-(3-oxobutyl)cyclohexanone

2-(1-hydroxypropan-2-yl)-5-methylcyclohexan-1-ol

2-(1-hydroxypropan-2-yl)-5-methylcyclohexan-1-ol

3(R)-methyl-6(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>-2(S)-(3-oxobutyl)cyclohexanone

3(R)-methyl-6(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>-2(S)-(3-oxobutyl)cyclohexanone

异蒲勒醇

3(R)-methyl-6(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>-2(S)-(3-oxobutyl)cyclohexanone

3(R)-methyl-6(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>-2(S)-(3-oxobutyl)cyclohexanone

上游原料

异蒲勒醇 (2S,3R,6S)-6-((R)-1-(benzyloxy)prop-2-yl)-3-methyl-2-((E)-3-(trimethylsilyl)but-2-en-1-yl)cyclohexanone

下游产品

<4a(S),8a(S)>-octahydro-5(R)-methyl-8(R)-<1(R)-methyl-2-hydroxyethyl>-2(1H)-naphthalenone (R)-2-{(1R,2S,3S,4R)-2-Formyl-4-methyl-3-[2-(2-methyl-[1,3]dithian-2-yl)-ethyl]-cyclohexyl}-propionic acid methyl ester 2-(4-methyl-7-oxo-(1α-H),2,3,(4β-H),(4aα-H),5,6,7,8,(8aα-H)-decahydronaphthalen-1-yl)propionic acid 1α,10α-methyl-7β-<2'β-(1'-benzyloxy)-propyl>-decalone-4 1α-Δ3-4,10α-dimethyl-7β-<2'β-(1'-benzyloxy)-propyl>-decalin 1α-Δ4-4,10α-dimethyl-7β-<2'β-(1'-benzyloxy)-propyl>-decalin (R)-2-((1R,4S,4aR,7R,9aS)-4a-Dimethoxymethyl-7-methoxy-1,7-dimethyl-octahydro-5,6-dioxa-benzocyclohepten-4-yl)-propionic acid methyl ester