百科

(S)-1-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethanol

(S)-1-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethanol

CAS号：94119-00-3

英文名：(S)-1-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethanol

分子式：C32H40O6Si

分子量：548.742

合成路线

苄基2,3-O-异亚丙基呋喃己糖i去

苄基2,3-O-异亚丙基呋喃己糖i去

(S)-1-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethanol

(S)-1-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethanol

1‐O‐benzyl‐2,3‐O‐isopropylidene‐5,6‐di‐O‐mesyl‐α‐D‐mannofuranose

1‐O‐benzyl‐2,3‐O‐isopropylidene‐5,6‐di‐O‐mesyl‐α‐D‐mannofuranose

(S)-1-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethanol

(S)-1-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethanol

5,6‐di‐O‐acetyl‐1‐O‐benzyl‐2,3‐O‐isopropylidene‐β‐L‐gulofuranose

5,6‐di‐O‐acetyl‐1‐O‐benzyl‐2,3‐O‐isopropylidene‐β‐L‐gulofuranose

(S)-1-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethanol

(S)-1-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethanol

上游原料

1‐O‐benzyl‐2,3‐O‐isopropylidene‐5,6‐di‐O‐mesyl‐α‐D‐mannofuranose 苄基2,3-O-异亚丙基呋喃己糖i去 5,6‐di‐O‐acetyl‐1‐O‐benzyl‐2,3‐O‐isopropylidene‐β‐L‐gulofuranose

下游产品

[(R)-2-Azido-2-((3aS,4R,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-ethoxy]-tert-butyl-diphenyl-silane 5‐azido‐1‐O‐benzyl‐5‐deoxy‐2,3‐O‐isopropylidene‐α‐D-mannofuranose benzyl 5-azido-5-deoxy-α-D-mannofuranoside