百科

Trifluoro-methanesulfonic acid (S)-1-((3aS,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester

Trifluoro-methanesulfonic acid (S)-1-((3aS,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester

CAS号：94119-01-4

英文名：Trifluoro-methanesulfonic acid (S)-1-((3aS,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester

分子式：C33H39F3O8SSi

分子量：680.804

合成路线

苄基2,3-O-异亚丙基呋喃己糖i去

苄基2,3-O-异亚丙基呋喃己糖i去

Trifluoro-methanesulfonic acid (S)-1-((3aS,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester

Trifluoro-methanesulfonic acid (S)-1-((3aS,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester

1‐O‐benzyl‐2,3‐O‐isopropylidene‐β‐L‐gulofuranose

1‐O‐benzyl‐2,3‐O‐isopropylidene‐β‐L‐gulofuranose

Trifluoro-methanesulfonic acid (S)-1-((3aS,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester

Trifluoro-methanesulfonic acid (S)-1-((3aS,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester

1‐O‐benzyl‐2,3‐O‐isopropylidene‐5,6‐di‐O‐mesyl‐α‐D‐mannofuranose

1‐O‐benzyl‐2,3‐O‐isopropylidene‐5,6‐di‐O‐mesyl‐α‐D‐mannofuranose

Trifluoro-methanesulfonic acid (S)-1-((3aS,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester

Trifluoro-methanesulfonic acid (S)-1-((3aS,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester

5,6‐di‐O‐acetyl‐1‐O‐benzyl‐2,3‐O‐isopropylidene‐β‐L‐gulofuranose

5,6‐di‐O‐acetyl‐1‐O‐benzyl‐2,3‐O‐isopropylidene‐β‐L‐gulofuranose

Trifluoro-methanesulfonic acid (S)-1-((3aS,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester

Trifluoro-methanesulfonic acid (S)-1-((3aS,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester

上游原料

1‐O‐benzyl‐2,3‐O‐isopropylidene‐β‐L‐gulofuranose 1‐O‐benzyl‐2,3‐O‐isopropylidene‐5,6‐di‐O‐mesyl‐α‐D‐mannofuranose 苄基2,3-O-异亚丙基呋喃己糖i去 5,6‐di‐O‐acetyl‐1‐O‐benzyl‐2,3‐O‐isopropylidene‐β‐L‐gulofuranose

下游产品

[(R)-2-Azido-2-((3aS,4R,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-ethoxy]-tert-butyl-diphenyl-silane 5‐azido‐1‐O‐benzyl‐5‐deoxy‐2,3‐O‐isopropylidene‐α‐D-mannofuranose benzyl 5-azido-5-deoxy-α-D-mannofuranoside