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(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

CAS号：942618-63-5

英文名：(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

分子式：C27H37NO6Si

分子量：499.671

合成路线

(1R,2S,2'S,3S,4R,6S)-4-acetoxy-1-(2'-benzyloxycarbonylamino-3'-tert-butyldiphenylsilyloxy-propyl)-2,3-epoxy-6-hydroxy-2-cyclohexen-1-ol

(1R,2S,2'S,3S,4R,6S)-4-acetoxy-1-(2'-benzyloxycarbonylamino-3'-tert-butyldiphenylsilyloxy-propyl)-2,3-epoxy-6-hydroxy-2-cyclohexen-1-ol

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(3S,5S,10S)-3-benzyloxycarbonylamino-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-ene-2,8-dione

(3S,5S,10S)-3-benzyloxycarbonylamino-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-ene-2,8-dione

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(3S,5S,8R,10S)-3-benzyloxycarbonylamino-8-hydroxy-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-en-2-one

(3S,5S,8R,10S)-3-benzyloxycarbonylamino-8-hydroxy-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-en-2-one

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(3S,5S,6R,7R,8R,10S)-3-benzyloxycarbonylamino-6,7-epoxy-8-hydroxy-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-en-2-one

(3S,5S,6R,7R,8R,10S)-3-benzyloxycarbonylamino-6,7-epoxy-8-hydroxy-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-en-2-one

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(3S,5S,8R,10S)-8-acetoxy-3-benzyloxycarbonylamino-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-en-2-one

(3S,5S,8R,10S)-8-acetoxy-3-benzyloxycarbonylamino-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-en-2-one

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2'S,4R,6S)-4-acetoxy-1-(2'-benzyloxycarbonylamino-3'-hydroxy-propyl)-6-hydroxy-2-cyclohexen-1-ol

(1S,2'S,4R,6S)-4-acetoxy-1-(2'-benzyloxycarbonylamino-3'-hydroxy-propyl)-6-hydroxy-2-cyclohexen-1-ol

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2'S,4R,6S)-4-acetoxy-1-(2'-benzyloxycarbonylamino-3'-tert-butyldiphenylsilyloxy-propyl)-6-hydroxy-2-cyclohexen-1-ol

(1S,2'S,4R,6S)-4-acetoxy-1-(2'-benzyloxycarbonylamino-3'-tert-butyldiphenylsilyloxy-propyl)-6-hydroxy-2-cyclohexen-1-ol

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(4S)-4-benzyloxycarbonylamino-6',7'-epoxy-1',3,4,4',4'a,8'a-hexahydrospiro[furan-2(5H),5'(8'H)-1',4'-methanonaphthalene]-5',8'-dione

(4S)-4-benzyloxycarbonylamino-6',7'-epoxy-1',3,4,4',4'a,8'a-hexahydrospiro[furan-2(5H),5'(8'H)-1',4'-methanonaphthalene]-5',8'-dione

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

benzyl ((1'S,2S,4S,4'R,4a'S,6'S,8a'R)-6'-hydroxy-5,8'-dioxo-4,4',4a',5,6',7',8',8a'-octahydro-1'H,3H-spiro[furan-2,5'-[1,4]methanonaphthalen]-4-yl)carbamate

benzyl ((1'S,2S,4S,4'R,4a'S,6'S,8a'R)-6'-hydroxy-5,8'-dioxo-4,4',4a',5,6',7',8',8a'-octahydro-1'H,3H-spiro[furan-2,5'-[1,4]methanonaphthalen]-4-yl)carbamate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,4R,4'S,4aS,5S,6S,8aR)-4'-benzyloxycarbonylamino-6-triethylsilyloxy-1,3',4',4,4a,6,7,8a-octahydrospiro[furan-2'(5H),5(8H)-1,4-methanonaphthalene]-5',8-dione

(1S,4R,4'S,4aS,5S,6S,8aR)-4'-benzyloxycarbonylamino-6-triethylsilyloxy-1,3',4',4,4a,6,7,8a-octahydrospiro[furan-2'(5H),5(8H)-1,4-methanonaphthalene]-5',8-dione

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

(1S,2R,4S,5R,6S)-5-((S)-2-amino-3-((tert-butyldiphenylsilyl)oxy)propyl)-4,5-dihydroxy-7-oxabicyclo[4.1.0]heptan-2-yl acetate

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上游原料

(1R,2S,2'S,3S,4R,6S)-4-acetoxy-1-(2'-benzyloxycarbonylamino-3'-tert-butyldiphenylsilyloxy-propyl)-2,3-epoxy-6-hydroxy-2-cyclohexen-1-ol (1S,2'S,4R,6S)-4-acetoxy-1-(2'-benzyloxycarbonylamino-3'-tert-butyldiphenylsilyloxy-propyl)-6-hydroxy-2-cyclohexen-1-ol benzyl ((1'S,2S,4S,4'R,4a'S,6'S,8a'R)-6'-hydroxy-5,8'-dioxo-4,4',4a',5,6',7',8',8a'-octahydro-1'H,3H-spiro[furan-2,5'-[1,4]methanonaphthalen]-4-yl)carbamate (3S,5S,8R,10S)-3-benzyloxycarbonylamino-8-hydroxy-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-en-2-one (1S,2'S,4R,6S)-4-acetoxy-1-(2'-benzyloxycarbonylamino-3'-hydroxy-propyl)-6-hydroxy-2-cyclohexen-1-ol (3S,5S,10S)-3-benzyloxycarbonylamino-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-ene-2,8-dione (1S,2'S,4R,6S)-4-acetoxy-1-(2'-benzyloxycarbonylamino-3'-hydroxy-propyl)-6-triethylsilyloxy-2-cyclohexen-1-ol (3S,5S,8R,10S)-8-acetoxy-3-benzyloxycarbonylamino-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-en-2-one (1S,4R,4'S,4aS,5S,6S,8aR)-4'-benzyloxycarbonylamino-6-triethylsilyloxy-1,3',4',4,4a,6,7,8a-octahydrospiro[furan-2'(5H),5(8H)-1,4-methanonaphthalene]-5',8-dione (4S)-4-benzyloxycarbonylamino-6',7'-epoxy-1',3,4,4',4'a,8'a-hexahydrospiro[furan-2(5H),5'(8'H)-1',4'-methanonaphthalene]-5',8'-dione (3S,5S,6R,7R,8R,10S)-3-benzyloxycarbonylamino-6,7-epoxy-8-hydroxy-10-triethylsilyloxy-1-oxaspiro[4,5]dec-6-en-2-one

下游产品

(2'S,2''E,4S,4''E,5S,6S,6''E,8''R,10''S,12''E,14''R)-4,5-epoxy-6-hydroxy-6-[3'-hydroxy-2'-(8'',10'',12'',14''-tetramethylhexadeca-2'',4'',6'',12''-tetraenoylamino)-propyl]-2-cyclohexen-1-one (2'S,2''E,4S,4''E,5S,6S,6''E,8''R,10''S,12''E,14''R)-4,5-epoxy-6-hydroxy-6-[2'-(8'',10'',12'',14''-tetramethylhexadeca-2'',4'',6'',12''-tetraenoylamino)-3'-tert-butyldiphenylsilyloxy-propyl]-2-cyclohexen-1-one (1R,2S,2'S,2''E,3S,4R,4''E,6S,6''E,8''R,10''S,12''E,14''R)-4-acetoxy-2,3-epoxy-6-hydroxy-1-[2'-(8'',10'',12'',14''-tetramethylhexadeca-2'',4'',6'',12''-tetraenoylamino)-3'-tert-butyldiphenylsilyloxy-propyl]-2-cyclohexan-1-ol