百科

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

CAS号：943718-56-7

英文名：(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

分子式：C17H26O5

分子量：310.385

合成路线

(S,E)-ethyl 5-(hydroxy)-6-(tosyloxy)hex-2-enoate

(S,E)-ethyl 5-(hydroxy)-6-(tosyloxy)hex-2-enoate

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(S)-hept-6-en-2-yl 3-((1R,2S,4S)-4-(methoxymethoxy)-2-vinylcyclopentyl)-3-oxopropanoate

(S)-hept-6-en-2-yl 3-((1R,2S,4S)-4-(methoxymethoxy)-2-vinylcyclopentyl)-3-oxopropanoate

(5S,10aS,12S,13aR,E)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(5S,10aS,12S,13aR,E)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(1R,2S,4S)-4-(methoxymethoxy)-2-vinylcyclopentanecarboxylic acid

(1R,2S,4S)-4-(methoxymethoxy)-2-vinylcyclopentanecarboxylic acid

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(S,E)-ethyl 5-(methoxymethoxy)-6-(tosyloxy)hex-2-enoate

(S,E)-ethyl 5-(methoxymethoxy)-6-(tosyloxy)hex-2-enoate

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(S,E)-ethyl 6-bromo-5-hydroxyhex-2-enoate

(S,E)-ethyl 6-bromo-5-hydroxyhex-2-enoate

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(S,E)-ethyl 6-bromo-5-(methoxymethoxy)hex-2-enoate

(S,E)-ethyl 6-bromo-5-(methoxymethoxy)hex-2-enoate

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

ethyl (1R,2S,4S)-4-(methoxymethoxy)-2-vinylcyclopentanecarboxylate

ethyl (1R,2S,4S)-4-(methoxymethoxy)-2-vinylcyclopentanecarboxylate

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

(5S,10aS,12S,13aR,Z)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione

上游原料

ethyl (1R,2S,4S)-4-(methoxymethoxy)-2-vinylcyclopentanecarboxylate (S,E)-ethyl 5-(hydroxy)-6-(tosyloxy)hex-2-enoate (1R,2S,4S)-4-(methoxymethoxy)-2-vinylcyclopentanecarboxylic acid (S)-hept-6-en-2-yl 3-((1R,2S,4S)-4-(methoxymethoxy)-2-vinylcyclopentyl)-3-oxopropanoate (S,E)-ethyl 6-bromo-5-(methoxymethoxy)hex-2-enoate (S,E)-ethyl 5-(methoxymethoxy)-6-(tosyloxy)hex-2-enoate (S,E)-ethyl 6-bromo-5-hydroxyhex-2-enoate

下游产品

(2E,6S,10E,11aS,13S,14aR)-13-(methoxymethoxy)-6-methyl-6,7,8,9,12,13,14,14a-octahydro-1H-cyclopenta[f][1]-oxacyclotridecine-1,4(11aH)-dione (5S,10aS,12S,13aR,E)-12-(methoxymethoxy)-5-methyl-6,7,8,10a,11,12,13,13a-octahydrocyclopenta[e][1]oxacyclododecine-1,3(2H,5H)-dione