百科

(6S,11aS,13S,14aR)-13-[tert-butyl(diphenyl)silyl]oxy-6-methyl-5,6,7,8,9,11a,12,13,14,14a-decahydrocyclopenta[f]azacyclotridecine-1,4-dione

(6S,11aS,13S,14aR)-13-[tert-butyl(diphenyl)silyl]oxy-6-methyl-5,6,7,8,9,11a,12,13,14,14a-decahydrocyclopenta[f]azacyclotridecine-1,4-dione

CAS号：943861-13-0

英文名：(6S,11aS,13S,14aR)-13-[tert-butyl(diphenyl)silyl]oxy-6-methyl-5,6,7,8,9,11a,12,13,14,14a-decahydrocyclopenta[f]azacyclotridecine-1,4-dione

分子式：C32H41NO3Si

分子量：515.758

合成路线

ethyl (E)-4-((1R,2S,4S)-2-((S,E)-6-((tert-butoxycarbonyl)amino)hept-1-en-1-yl)-4-((tert-butyldiphenylsilyl)oxy)cyclopentyl)-4-oxobut-2-enoate

ethyl (E)-4-((1R,2S,4S)-2-((S,E)-6-((tert-butoxycarbonyl)amino)hept-1-en-1-yl)-4-((tert-butyldiphenylsilyl)oxy)cyclopentyl)-4-oxobut-2-enoate

(6S,11aS,13S,14aR)-13-[tert-butyl(diphenyl)silyl]oxy-6-methyl-5,6,7,8,9,11a,12,13,14,14a-decahydrocyclopenta[f]azacyclotridecine-1,4-dione

(6S,11aS,13S,14aR)-13-[tert-butyl(diphenyl)silyl]oxy-6-methyl-5,6,7,8,9,11a,12,13,14,14a-decahydrocyclopenta[f]azacyclotridecine-1,4-dione

(1S,4S,5S)-5-Vinyl-2-oxa-bicyclo[2.2.1]heptan-3-one

(1S,4S,5S)-5-Vinyl-2-oxa-bicyclo[2.2.1]heptan-3-one

(6S,11aS,13S,14aR)-13-[tert-butyl(diphenyl)silyl]oxy-6-methyl-5,6,7,8,9,11a,12,13,14,14a-decahydrocyclopenta[f]azacyclotridecine-1,4-dione

(6S,11aS,13S,14aR)-13-[tert-butyl(diphenyl)silyl]oxy-6-methyl-5,6,7,8,9,11a,12,13,14,14a-decahydrocyclopenta[f]azacyclotridecine-1,4-dione

tert-butyl N-(1S,5E)-1-methyl-6-[(1S,4R,5S)-3-oxo-2-oxabicyclo[2.2.1]hept-5-yl]-5-hexenylcarbamate

tert-butyl N-(1S,5E)-1-methyl-6-[(1S,4R,5S)-3-oxo-2-oxabicyclo[2.2.1]hept-5-yl]-5-hexenylcarbamate

(6S,11aS,13S,14aR)-13-[tert-butyl(diphenyl)silyl]oxy-6-methyl-5,6,7,8,9,11a,12,13,14,14a-decahydrocyclopenta[f]azacyclotridecine-1,4-dione

(6S,11aS,13S,14aR)-13-[tert-butyl(diphenyl)silyl]oxy-6-methyl-5,6,7,8,9,11a,12,13,14,14a-decahydrocyclopenta[f]azacyclotridecine-1,4-dione

上游原料

ethyl (E)-4-((1R,2S,4S)-2-((S,E)-6-((tert-butoxycarbonyl)amino)hept-1-en-1-yl)-4-((tert-butyldiphenylsilyl)oxy)cyclopentyl)-4-oxobut-2-enoate (1S,4S,5S)-5-Vinyl-2-oxa-bicyclo[2.2.1]heptan-3-one tert-butyl N-(1S,5E)-1-methyl-6-[(1S,4R,5S)-3-oxo-2-oxabicyclo[2.2.1]hept-5-yl]-5-hexenylcarbamate

下游产品

(1R,6S,11aS,13S,14aR)-13-[tert-butyl(diphenyl)silyl]oxy-1-hydroxy-6-methyl-5,6,7,8,9,11a,12,13,14,14a-decahydrocyclopenta[f]azacyclotridecin-4(1H)-one