百科

1-((2S,5S,6R)-6-(2-((tert-butyldimethylsilyl)oxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)-6-methylhept-3-yn-2-one

1-((2S,5S,6R)-6-(2-((tert-butyldimethylsilyl)oxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)-6-methylhept-3-yn-2-one

CAS号：944831-34-9

英文名：1-((2S,5S,6R)-6-(2-((tert-butyldimethylsilyl)oxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)-6-methylhept-3-yn-2-one

分子式：C22H40O3Si

分子量：380.637

合成路线

acrylic acid 1-[2-(tert-butyldimethylsilanyloxy)ethyl]-2-methylbut-3-enyl ester

acrylic acid 1-[2-(tert-butyldimethylsilanyloxy)ethyl]-2-methylbut-3-enyl ester

1-((2S,5S,6R)-6-(2-((tert-butyldimethylsilyl)oxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)-6-methylhept-3-yn-2-one

1-((2S,5S,6R)-6-(2-((tert-butyldimethylsilyl)oxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)-6-methylhept-3-yn-2-one

6-[2-(tert-butyldimethylsilanyloxy)ethyl]-5-methyltetrahydropyran-2-one

6-[2-(tert-butyldimethylsilanyloxy)ethyl]-5-methyltetrahydropyran-2-one

1-((2S,5S,6R)-6-(2-((tert-butyldimethylsilyl)oxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)-6-methylhept-3-yn-2-one

1-((2S,5S,6R)-6-(2-((tert-butyldimethylsilyl)oxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)-6-methylhept-3-yn-2-one

(3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol

(3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol

1-((2S,5S,6R)-6-(2-((tert-butyldimethylsilyl)oxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)-6-methylhept-3-yn-2-one

1-((2S,5S,6R)-6-(2-((tert-butyldimethylsilyl)oxy)ethyl)-5-methyltetrahydro-2H-pyran-2-yl)-6-methylhept-3-yn-2-one

上游原料

acrylic acid 1-[2-(tert-butyldimethylsilanyloxy)ethyl]-2-methylbut-3-enyl ester 6-[2-(tert-butyldimethylsilanyloxy)ethyl]-5-methyltetrahydropyran-2-one (3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol

下游产品

(S)-1-((2R,3S,6S)-6-((R,E)-2-((tert-butyldimethylsilyl)oxy)-6-methylhept-3-en-1-yl)-3-methyltetrahydro-2H-pyran-2-yl)pent-4-en-2-ol 9-{6-[2-(tert-butyldimethylsilanyloxy)-6-methylhept-3-enyl]-3-methyltetrahydropyran-2-yl}-8-methoxynon-1-ene-4,6-diol 2-{6-[2-(tert-butyldimethylsilanyloxy)-6-methylhept-3-enyl]-3-methyltetrahydropyran-2-yl}ethanol