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(3aR,9S,9aS,9bS)-9-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-1,3-dioxolo[4,5-a]indolizidine

(3aR,9S,9aS,9bS)-9-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-1,3-dioxolo[4,5-a]indolizidine

CAS号：945406-31-5

英文名：(3aR,9S,9aS,9bS)-9-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-1,3-dioxolo[4,5-a]indolizidine

分子式：C17H33NO3Si

分子量：327.534

合成路线

5-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-N-diphenylmethyl-1,4,6,7,8-pentadeoxy-1,4-imino-D-gulo-oct-7-enitol

5-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-N-diphenylmethyl-1,4,6,7,8-pentadeoxy-1,4-imino-D-gulo-oct-7-enitol

(3aR,9S,9aS,9bS)-9-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-1,3-dioxolo[4,5-a]indolizidine

(3aR,9S,9aS,9bS)-9-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-1,3-dioxolo[4,5-a]indolizidine

2,3-O-isopropylidene-N-diphenylmethyl-1,4,6,7,8-pentadeoxy-1,4-imino-D-gulo-oct-7-enitol

2,3-O-isopropylidene-N-diphenylmethyl-1,4,6,7,8-pentadeoxy-1,4-imino-D-gulo-oct-7-enitol

(3aR,9S,9aS,9bS)-9-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-1,3-dioxolo[4,5-a]indolizidine

(3aR,9S,9aS,9bS)-9-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-1,3-dioxolo[4,5-a]indolizidine

5-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-N-diphenylmethyl-1,4,6,7-tetradeoxy-1,4-imino-D-gulo-octitol

5-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-N-diphenylmethyl-1,4,6,7-tetradeoxy-1,4-imino-D-gulo-octitol

(3aR,9S,9aS,9bS)-9-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-1,3-dioxolo[4,5-a]indolizidine

(3aR,9S,9aS,9bS)-9-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-1,3-dioxolo[4,5-a]indolizidine

Methanesulfonic acid (S)-4-((3aS,4S,6aR)-5-benzhydryl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrol-4-yl)-4-(tert-butyl-dimethyl-silanyloxy)-butyl ester

Methanesulfonic acid (S)-4-((3aS,4S,6aR)-5-benzhydryl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrol-4-yl)-4-(tert-butyl-dimethyl-silanyloxy)-butyl ester

(3aR,9S,9aS,9bS)-9-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-1,3-dioxolo[4,5-a]indolizidine

(3aR,9S,9aS,9bS)-9-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-octahydro-1,3-dioxolo[4,5-a]indolizidine

上游原料

5-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-N-diphenylmethyl-1,4,6,7-tetradeoxy-1,4-imino-D-gulo-octitol 2,3-O-isopropylidene-N-diphenylmethyl-1,4,6,7,8-pentadeoxy-1,4-imino-D-gulo-oct-7-enitol 5-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-N-diphenylmethyl-1,4,6,7,8-pentadeoxy-1,4-imino-D-gulo-oct-7-enitol Methanesulfonic acid (S)-4-((3aS,4S,6aR)-5-benzhydryl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrol-4-yl)-4-(tert-butyl-dimethyl-silanyloxy)-butyl ester

下游产品

(1S,2R,8S,8aR)-1,2,8-triacetoxyindolizine