百科

((2R,3R,4S,5S,6S)-6-(((2R,3R,4R,5S,6S)-6-(allyloxy)-3,4-bis(benzyloxy)-5-hydroxytetrahydro-2H-pyran-2-yl)methoxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

((2R,3R,4S,5S,6S)-6-(((2R,3R,4R,5S,6S)-6-(allyloxy)-3,4-bis(benzyloxy)-5-hydroxytetrahydro-2H-pyran-2-yl)methoxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

CAS号：947251-31-2

英文名：((2R,3R,4S,5S,6S)-6-(((2R,3R,4R,5S,6S)-6-(allyloxy)-3,4-bis(benzyloxy)-5-hydroxytetrahydro-2H-pyran-2-yl)methoxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

分子式：C57H58O13

分子量：951.063

合成路线

allyl 3,4-di-O-benzyl-α-D-mannopyranoside

allyl 3,4-di-O-benzyl-α-D-mannopyranoside

2,3-di-O-benzyl-6-O-benzoyl-β-D-mannopyranose 1,2-(pent-4-enyl orthobenzoate)

2,3-di-O-benzyl-6-O-benzoyl-β-D-mannopyranose 1,2-(pent-4-enyl orthobenzoate)

((2R,3R,4S,5S,6S)-6-(((2R,3R,4R,5S,6S)-6-(allyloxy)-3,4-bis(benzyloxy)-5-hydroxytetrahydro-2H-pyran-2-yl)methoxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

((2R,3R,4S,5S,6S)-6-(((2R,3R,4R,5S,6S)-6-(allyloxy)-3,4-bis(benzyloxy)-5-hydroxytetrahydro-2H-pyran-2-yl)methoxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

2,3-di-O-benzyl-6-O-benzoyl-β-D-mannopyranose 1,2-(pent-4-enyl orthobenzoate)

2,3-di-O-benzyl-6-O-benzoyl-β-D-mannopyranose 1,2-(pent-4-enyl orthobenzoate)

((2R,3R,4S,5S,6S)-6-(((2R,3R,4R,5S,6S)-6-(allyloxy)-3,4-bis(benzyloxy)-5-hydroxytetrahydro-2H-pyran-2-yl)methoxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

((2R,3R,4S,5S,6S)-6-(((2R,3R,4R,5S,6S)-6-(allyloxy)-3,4-bis(benzyloxy)-5-hydroxytetrahydro-2H-pyran-2-yl)methoxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

((2R,3R,4S,5S,6S)-6-(allyloxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

((2R,3R,4S,5S,6S)-6-(allyloxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

((2R,3R,4S,5S,6S)-6-(((2R,3R,4R,5S,6S)-6-(allyloxy)-3,4-bis(benzyloxy)-5-hydroxytetrahydro-2H-pyran-2-yl)methoxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

((2R,3R,4S,5S,6S)-6-(((2R,3R,4R,5S,6S)-6-(allyloxy)-3,4-bis(benzyloxy)-5-hydroxytetrahydro-2H-pyran-2-yl)methoxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

上游原料

allyl 3,4-di-O-benzyl-α-D-mannopyranoside 2,3-di-O-benzyl-6-O-benzoyl-β-D-mannopyranose 1,2-(pent-4-enyl orthobenzoate) ((2R,3R,4S,5S,6S)-6-(allyloxy)-5-(benzoyloxy)-3,4-bis(benzyloxy)tetrahydro-2H-pyran-2-yl)methyl benzoate

下游产品

allyl 3,4-di-O-benzyl-6-O-(3,4-di-O-benzyl-α-D-mannopyranosyl)-α-D-mannopyranoside