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(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

CAS号：947661-45-2

英文名：(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

分子式：C21H44O2Si2

分子量：384.744

合成路线

((2R,3R)-3-(3-(benzyloxy)propyl)oxiran-2-yl)methanol

((2R,3R)-3-(3-(benzyloxy)propyl)oxiran-2-yl)methanol

(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

(2S,3R)-2-(3-(benzyloxy)propyl)-3-(iodomethyl)oxirane

(2S,3R)-2-(3-(benzyloxy)propyl)-3-(iodomethyl)oxirane

(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

((((4S)-4-(2-bromo-1-ethoxyethoxy)hex-5-en-1-yl)oxy)methyl)benzene

((((4S)-4-(2-bromo-1-ethoxyethoxy)hex-5-en-1-yl)oxy)methyl)benzene

(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

(4R,5S)-5-(3-(benzyloxy)propyl)-4-methyldihydrofuran-2(3H)-one

(4R,5S)-5-(3-(benzyloxy)propyl)-4-methyldihydrofuran-2(3H)-one

(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

(S)-6-(benzyloxy)hex-1-en-3-ol

(S)-6-(benzyloxy)hex-1-en-3-ol

(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

(S)-2,2,3,3,10,10,11,11-octamethyl-5-((R)-pent-4-yn-2-yl)-4,9-dioxa-3,10-disiladodecane

上游原料

(4R,5S)-5-(3-(benzyloxy)propyl)-4-methyldihydrofuran-2(3H)-one (2S,3R)-2-(3-(benzyloxy)propyl)-3-(iodomethyl)oxirane ((((4S)-4-(2-bromo-1-ethoxyethoxy)hex-5-en-1-yl)oxy)methyl)benzene (S)-6-(benzyloxy)hex-1-en-3-ol ((2R,3R)-3-(3-(benzyloxy)propyl)oxiran-2-yl)methanol

下游产品

(2R,10S,Z)-1-((2R,3R,5S)-5-((benzyloxy)methyl)-3-((tert-butyldimethylsilyl)oxy)tetrahydrofuran-2-yl)-10-((tert-butyldimethylsilyl)oxy)-11-((4-methoxybenzyl)oxy)-2-methylundec-8-ene-3,6-dione (2R,3S)-1-((2R,3R,5S)-5-((benzyloxy)methyl)-3-((tert-butyldimethylsilyl)oxy)tetrahydrofuran-2-yl)-2-methylhept-6-en-3-ol (2R,3S,10S)-1-((2R,3R,5S)-5-((benzyloxy)methyl)-3-((tert-butyldimethylsilyl)oxy)tetrahydrofuran-2-yl)-10-((tert-butyldimethylsilyl)oxy)-11-((4-methoxybenzyl)oxy)-2-methylundec-8-yne-3,6-diol (5S,12S)-5-((R)-1-((2R,3R,5S)-5-((benzyloxy)methyl)-3-((tert-butyldimethylsilyl)oxy)tetrahydrofuran-2-yl)propan-2-yl)-3,3-diethyl-12-(((4-methoxybenzyl)oxy)methyl)-14,14,15,15-tetramethyl-4,13-dioxa-3,14-disilahexadec-10-yn-8-ol