百科

(2S,3S,4R,5R,6R)-2-allyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydro-4H-pyran

(2S,3S,4R,5R,6R)-2-allyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydro-4H-pyran

CAS号：948036-08-6

英文名：(2S,3S,4R,5R,6R)-2-allyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydro-4H-pyran

分子式：C36H48O6Si

分子量：604.848

合成路线

allyl 2,4-di-O-benzyl-α-D-mannopyranoside

allyl 2,4-di-O-benzyl-α-D-mannopyranoside

(2S,3S,4R,5R,6R)-2-allyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydro-4H-pyran

(2S,3S,4R,5R,6R)-2-allyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydro-4H-pyran

(2S,3S,4S,5S,6R)-2-allyloxy-3,5-bisbenzyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-tetrahydro-4H-pyran-4-ol

(2S,3S,4S,5S,6R)-2-allyloxy-3,5-bisbenzyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-tetrahydro-4H-pyran-4-ol

(2S,3S,4R,5R,6R)-2-allyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydro-4H-pyran

(2S,3S,4R,5R,6R)-2-allyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydro-4H-pyran

(2S,3S,4S,5R,6R)-2-allyloxy-3,5-bisbenzyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-4-trifluoromethanesulfonyloxy-tetrahydro-4H-pyran

(2S,3S,4S,5R,6R)-2-allyloxy-3,5-bisbenzyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-4-trifluoromethanesulfonyloxy-tetrahydro-4H-pyran

(2S,3S,4R,5R,6R)-2-allyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydro-4H-pyran

(2S,3S,4R,5R,6R)-2-allyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydro-4H-pyran

(2S,3S,4R,5R,6R)-2-allyloxy-3,5-bisbenzyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-tetrahydro-4H-pyran-4-yl acetate

(2S,3S,4R,5R,6R)-2-allyloxy-3,5-bisbenzyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-tetrahydro-4H-pyran-4-yl acetate

(2S,3S,4R,5R,6R)-2-allyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydro-4H-pyran

(2S,3S,4R,5R,6R)-2-allyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydro-4H-pyran

上游原料

allyl 2,4-di-O-benzyl-α-D-mannopyranoside (2S,3S,4S,5R,6R)-2-allyloxy-3,5-bisbenzyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-4-trifluoromethanesulfonyloxy-tetrahydro-4H-pyran (2S,3S,4S,5S,6R)-2-allyloxy-3,5-bisbenzyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-tetrahydro-4H-pyran-4-ol (2S,3S,4R,5R,6R)-2-allyloxy-3,5-bisbenzyloxy-6-[(tert-butyldimethylsilyl)oxy]methyl-tetrahydro-4H-pyran-4-yl acetate

下游产品

(1R,2R,3R,4S,5R)-2,3,4-tris(benzyloxy)-5-vinyl-6,8-dioxabicyclo[3.2.1]octane (3S,4R,5R,6R)-6-[(tert-butyldimethylsilyl)oxy]methyl-3,4,5-trisbenzyloxy-tetrahydropyran-2-one 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-C-vinyl-D-altropyranose