百科

(3R)-3-{(1R,2R)-2-[(tert-butyldiphenylsilanyloxy)methyl]cyclopropyl}-N-methoxy-N-methyl-3-(triethylsilanyloxy)propionamide

(3R)-3-{(1R,2R)-2-[(tert-butyldiphenylsilanyloxy)methyl]cyclopropyl}-N-methoxy-N-methyl-3-(triethylsilanyloxy)propionamide

CAS号：950588-58-6

英文名：(3R)-3-{(1R,2R)-2-[(tert-butyldiphenylsilanyloxy)methyl]cyclopropyl}-N-methoxy-N-methyl-3-(triethylsilanyloxy)propionamide

分子式：C31H49NO4Si2

分子量：555.896

合成路线

(3R)-6-(tert-butyldiphenylsilanyloxy)-3-hydroxy-1-[(4S)-4-isopropyl-2-thioxothiazolidin-3-yl]hex-4-en-1-one

(3R)-6-(tert-butyldiphenylsilanyloxy)-3-hydroxy-1-[(4S)-4-isopropyl-2-thioxothiazolidin-3-yl]hex-4-en-1-one

(3R)-3-{(1R,2R)-2-[(tert-butyldiphenylsilanyloxy)methyl]cyclopropyl}-N-methoxy-N-methyl-3-(triethylsilanyloxy)propionamide

(3R)-3-{(1R,2R)-2-[(tert-butyldiphenylsilanyloxy)methyl]cyclopropyl}-N-methoxy-N-methyl-3-(triethylsilanyloxy)propionamide

(3R)-6-(tert-butyldiphenylsilanyloxy)-3-hydroxyhex-4-enoic acid N-methoxy-N-methylamide

(3R)-6-(tert-butyldiphenylsilanyloxy)-3-hydroxyhex-4-enoic acid N-methoxy-N-methylamide

(3R)-3-{(1R,2R)-2-[(tert-butyldiphenylsilanyloxy)methyl]cyclopropyl}-N-methoxy-N-methyl-3-(triethylsilanyloxy)propionamide

(3R)-3-{(1R,2R)-2-[(tert-butyldiphenylsilanyloxy)methyl]cyclopropyl}-N-methoxy-N-methyl-3-(triethylsilanyloxy)propionamide

cis-4-(tert-butyl-diphenylsilanyloxy)-but-2-enal

cis-4-(tert-butyl-diphenylsilanyloxy)-but-2-enal

(3R)-3-{(1R,2R)-2-[(tert-butyldiphenylsilanyloxy)methyl]cyclopropyl}-N-methoxy-N-methyl-3-(triethylsilanyloxy)propionamide

(3R)-3-{(1R,2R)-2-[(tert-butyldiphenylsilanyloxy)methyl]cyclopropyl}-N-methoxy-N-methyl-3-(triethylsilanyloxy)propionamide

上游原料

(3R)-6-(tert-butyldiphenylsilanyloxy)-3-hydroxy-1-[(4S)-4-isopropyl-2-thioxothiazolidin-3-yl]hex-4-en-1-one cis-4-(tert-butyl-diphenylsilanyloxy)-but-2-enal (3R)-6-(tert-butyldiphenylsilanyloxy)-3-hydroxyhex-4-enoic acid N-methoxy-N-methylamide

下游产品

(5R)-5-{(1R,2R)-2-[(tert-butyldiphenylsilanyloxy)methyl]cyclopropyl}-5-hydroxypent-1-en-3-ol (5R)-5-{(1R,2R)-2-[(tert-butyldiphenylsilanyloxy)methyl]cyclopropyl}-5-(triethylsilanyloxy)pent-1-en-3-ol (4R)-4-[(1R,2R)-2-(tert-butyldiphenylsilanyloxymethyl)cyclopropyl]-6-vinyl-[1,3]-dioxan-2-one