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(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

CAS号：95218-57-8

英文名：(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

分子式：C16H25IO3

分子量：392.272

合成路线

(7R,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxymethyl)-7-methyl-3,7,8,8a-tetrahydro-2H-naphthalen-1-one

(7R,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxymethyl)-7-methyl-3,7,8,8a-tetrahydro-2H-naphthalen-1-one

(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,4SR,8aRS)-1-<<(tert-butyldimethylsilyl)oxy>methyl>-8-(1,3-dithian-2-yl)-4-hydroxy-2-methyl-1,2,3,4,6,7,8,8a-octahydronaphthalene

(1SR,2SR,4SR,8aRS)-1-<<(tert-butyldimethylsilyl)oxy>methyl>-8-(1,3-dithian-2-yl)-4-hydroxy-2-methyl-1,2,3,4,6,7,8,8a-octahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-<<(tert-butyldimethylsilyl)oxy>methyl>-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-<<(tert-butyldimethylsilyl)oxy>methyl>-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-<<(methylsulfonyl)oxy>methyl>-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-<<(methylsulfonyl)oxy>methyl>-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

<(2,4,6-triisopropylphenyl)sulfonyl>hydrazone of (1SR,2SR,8aRS)-8-(1,3-dithian-2-yl)-1-(hydroxymethyl)-2-methyl-4-oxo-1,2,3,4,6,7,8,8a-octahydronaphthalene

<(2,4,6-triisopropylphenyl)sulfonyl>hydrazone of (1SR,2SR,8aRS)-8-(1,3-dithian-2-yl)-1-(hydroxymethyl)-2-methyl-4-oxo-1,2,3,4,6,7,8,8a-octahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

(1SR,2SR,8SR,8aRS)-1-(iodomethyl)-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

上游原料

(7R,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxymethyl)-7-methyl-3,7,8,8a-tetrahydro-2H-naphthalen-1-one <(2,4,6-triisopropylphenyl)sulfonyl>hydrazone of (1SR,2SR,8aRS)-8-(1,3-dithian-2-yl)-1-(hydroxymethyl)-2-methyl-4-oxo-1,2,3,4,6,7,8,8a-octahydronaphthalene (1SR,2SR,4SR,8aRS)-1-<<(tert-butyldimethylsilyl)oxy>methyl>-8-(1,3-dithian-2-yl)-4-hydroxy-2-methyl-1,2,3,4,6,7,8,8a-octahydronaphthalene (1SR,2SR,8SR,8aRS)-1-<<(tert-butyldimethylsilyl)oxy>methyl>-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene (1SR,2SR,8SR,8aRS)-1-<<(methylsulfonyl)oxy>methyl>-8-<(2-methoxyethoxy)methoxy>-2-methyl-1,2,6,7,8,8a-hexahydronaphthalene

下游产品

(2aS,3S,8aS,8bR)-3-Methyl-2a,3,7,8,8a,8b-hexahydro-2H-naphtho[1,8-bc]furan (1SR,2SR,8SR,8aRS)-2-methyl-8-<(2-methoxyethoxy)methoxy>-1-<(triphenylphosphonio)methyl>-1,2,6,7,8,8a-hexahydronaphthalene iodide