百科

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

CAS号：953047-19-3

英文名：((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

分子式：C17H35IO3Si

分子量：442.448

合成路线

ethyl (R,E)-5-(tert-butyldimethylsilyloxy)oct-2-enoate

ethyl (R,E)-5-(tert-butyldimethylsilyloxy)oct-2-enoate

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

(R)-(tert-butyl)(hept-1-en-4-yloxy)dimethylsilane

(R)-(tert-butyl)(hept-1-en-4-yloxy)dimethylsilane

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

(3R)-3-{[(tert-butyl)dimethylsilyl]oxy}hexanal

(3R)-3-{[(tert-butyl)dimethylsilyl]oxy}hexanal

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

953047-23-9

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

ethyl (2S,3R,5R)-5-(tert-butyldimethylsilyloxy)-2,3-dihydroxyoctanoate

ethyl (2S,3R,5R)-5-(tert-butyldimethylsilyloxy)-2,3-dihydroxyoctanoate

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

ethyl (4S,5R)-5-((R)-2-(tert-butyldimethylsilyloxy)pentyl)-2,2-dimethyl-1,3-dioxolane-4-carboxylate

ethyl (4S,5R)-5-((R)-2-(tert-butyldimethylsilyloxy)pentyl)-2,2-dimethyl-1,3-dioxolane-4-carboxylate

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

((4R,5R)-5-((R)-2-(tert-butyldimethylsilyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol

((4R,5R)-5-((R)-2-(tert-butyldimethylsilyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

((R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)pent-2-yloxy)(tert-butyl)dimethylsilane

上游原料

ethyl (4S,5R)-5-((R)-2-(tert-butyldimethylsilyloxy)pentyl)-2,2-dimethyl-1,3-dioxolane-4-carboxylate ethyl (2S,3R,5R)-5-(tert-butyldimethylsilyloxy)-2,3-dihydroxyoctanoate (R)-(tert-butyl)(hept-1-en-4-yloxy)dimethylsilane ((4R,5R)-5-((R)-2-(tert-butyldimethylsilyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol (3R)-3-{[(tert-butyl)dimethylsilyl]oxy}hexanal ethyl (R,E)-5-(tert-butyldimethylsilyloxy)oct-2-enoate

下游产品

(tert-butyl)((4R,6R)-6-(4-methoxybenzyloxy)oct-7-en-4-yloxy)dimethylsilane (3R,5R)-5-(tert-butyldimethylsilyloxy)oct-1-en-3-ol (4R,6R)-6-(4-methoxybenzyloxy)oct-7-en-4-ol