百科

tert-butyl (9aS,11R,13aS)-11-methyl-13-oxo-2,3,6,7,9,9a,10,11,12,13-decahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

tert-butyl (9aS,11R,13aS)-11-methyl-13-oxo-2,3,6,7,9,9a,10,11,12,13-decahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

CAS号：960072-34-8

英文名：tert-butyl (9aS,11R,13aS)-11-methyl-13-oxo-2,3,6,7,9,9a,10,11,12,13-decahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

分子式：C21H33NO3

分子量：347.492

合成路线

(3aS,6R,7aR)-3a-allyl-6-methylhexahydrospiro[indene-4,2'-[1,3]dioxolan]-3(3aH)-one

(3aS,6R,7aR)-3a-allyl-6-methylhexahydrospiro[indene-4,2'-[1,3]dioxolan]-3(3aH)-one

tert-butyl (9aS,11R,13aS)-11-methyl-13-oxo-2,3,6,7,9,9a,10,11,12,13-decahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

tert-butyl (9aS,11R,13aS)-11-methyl-13-oxo-2,3,6,7,9,9a,10,11,12,13-decahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

(((3R,5R)-3-(2-(1,3-dioxolan-2-yl)ethyl)-2-allyl-5-methylcyclohex-1-en-1-yl)oxy)trimethylsilane

(((3R,5R)-3-(2-(1,3-dioxolan-2-yl)ethyl)-2-allyl-5-methylcyclohex-1-en-1-yl)oxy)trimethylsilane

tert-butyl (9aS,11R,13aS)-11-methyl-13-oxo-2,3,6,7,9,9a,10,11,12,13-decahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

tert-butyl (9aS,11R,13aS)-11-methyl-13-oxo-2,3,6,7,9,9a,10,11,12,13-decahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

(-)-(R)-5-methyl-2-allyl-2-cyclohexenone

(-)-(R)-5-methyl-2-allyl-2-cyclohexenone

tert-butyl (9aS,11R,13aS)-11-methyl-13-oxo-2,3,6,7,9,9a,10,11,12,13-decahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

tert-butyl (9aS,11R,13aS)-11-methyl-13-oxo-2,3,6,7,9,9a,10,11,12,13-decahydro-1H-indeno[1,7a-e]azonine-4(5H)-carboxylate

上游原料

(-)-(R)-5-methyl-2-allyl-2-cyclohexenone (3aS,6R,7aR)-3a-allyl-6-methylhexahydrospiro[indene-4,2'-[1,3]dioxolan]-3(3aH)-one (((3R,5R)-3-(2-(1,3-dioxolan-2-yl)ethyl)-2-allyl-5-methylcyclohex-1-en-1-yl)oxy)trimethylsilane

下游产品

2-((1S,3R,6S)-10-(tert-butoxycarbonyl)-3-methyl-5,14-dioxo-10-azaspiro[5.8]tetradecan-1-yl)acetic acid