百科

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

CAS号：960211-24-9

英文名：ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

分子式：C21H36O4Si

分子量：380.594

合成路线

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-11-hydroxy-6,8-dimethylundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-11-hydroxy-6,8-dimethylundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

(2R,3S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-pentanal

(2R,3S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-pentanal

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

(4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-enal

(4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-enal

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

(4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-en-1-ol

(4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-en-1-ol

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

ethyl (4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-enoate

ethyl (4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-enoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9,11-bis((tert-butyldimethylsilyl)oxy)-6,8-dimethylundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9,11-bis((tert-butyldimethylsilyl)oxy)-6,8-dimethylundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

(2S,3S)-3,5-bis{[(tert-butyl)dimethylsilyl]oxy}-2-methylpentan-1-ol

(2S,3S)-3,5-bis{[(tert-butyl)dimethylsilyl]oxy}-2-methylpentan-1-ol

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

上游原料

(4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-en-1-ol ethyl (2E,4E,6E,8S,9S)-9,11-bis((tert-butyldimethylsilyl)oxy)-6,8-dimethylundeca-2,4,6-trienoate (4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-enal ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-11-hydroxy-6,8-dimethylundeca-2,4,6-trienoate (2S,3S)-3,5-bis{[(tert-butyl)dimethylsilyl]oxy}-2-methylpentan-1-ol (2R,3S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-pentanal ethyl (4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-enoate

下游产品

1-ethyl 13-methyl (2E,4E,6E,8S,9S,11E)-9-((tert-butyldimethylsilyl)oxy)-12-methoxy-6,8-dimethyltrideca-2,4,6,11-tetraenedioate (S,2E,4E,6E)-8-((S)-5-methoxy-6-oxo-3,6-dihydro-2H-pyran-2-yl)-6-methylnona-2,4,6-trienoic acid