百科

1-ethyl 13-methyl (2E,4E,6E,8S,9S,11E)-9-((tert-butyldimethylsilyl)oxy)-12-methoxy-6,8-dimethyltrideca-2,4,6,11-tetraenedioate

1-ethyl 13-methyl (2E,4E,6E,8S,9S,11E)-9-((tert-butyldimethylsilyl)oxy)-12-methoxy-6,8-dimethyltrideca-2,4,6,11-tetraenedioate

CAS号：960211-25-0

英文名：1-ethyl 13-methyl (2E,4E,6E,8S,9S,11E)-9-((tert-butyldimethylsilyl)oxy)-12-methoxy-6,8-dimethyltrideca-2,4,6,11-tetraenedioate

分子式：C25H42O6Si

分子量：466.683

合成路线

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

1-ethyl 13-methyl (2E,4E,6E,8S,9S,11E)-9-((tert-butyldimethylsilyl)oxy)-12-methoxy-6,8-dimethyltrideca-2,4,6,11-tetraenedioate

1-ethyl 13-methyl (2E,4E,6E,8S,9S,11E)-9-((tert-butyldimethylsilyl)oxy)-12-methoxy-6,8-dimethyltrideca-2,4,6,11-tetraenedioate

(4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-enal

(4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-enal

1-ethyl 13-methyl (2E,4E,6E,8S,9S,11E)-9-((tert-butyldimethylsilyl)oxy)-12-methoxy-6,8-dimethyltrideca-2,4,6,11-tetraenedioate

1-ethyl 13-methyl (2E,4E,6E,8S,9S,11E)-9-((tert-butyldimethylsilyl)oxy)-12-methoxy-6,8-dimethyltrideca-2,4,6,11-tetraenedioate

上游原料

(4S,5S,E)-5,7-bis((tert-butyldimethylsilyl)oxy)-2,4-dimethylhept-2-enal ethyl (2E,4E,6E,8S,9S)-9-((tert-butyldimethylsilyl)oxy)-6,8-dimethyl-11-oxoundeca-2,4,6-trienoate

下游产品

(S,2E,4E,6E)-8-((S)-5-methoxy-6-oxo-3,6-dihydro-2H-pyran-2-yl)-6-methylnona-2,4,6-trienoic acid