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ethyl (5S)-(6E)-5-tert-butyldiphenylsilyloxy-7-formyl-6-heptenoate

ethyl (5S)-(6E)-5-tert-butyldiphenylsilyloxy-7-formyl-6-heptenoate

CAS号：98009-24-6

英文名：ethyl (5S)-(6E)-5-tert-butyldiphenylsilyloxy-7-formyl-6-heptenoate

分子式：C26H34O4Si

分子量：438.631

合成路线

2,2'-dimethyl-1-(4'(R)-1',3'-dioxacyclopentyl)-but-3-yn-1(S/R)-ol

2,2'-dimethyl-1-(4'(R)-1',3'-dioxacyclopentyl)-but-3-yn-1(S/R)-ol

ethyl (5S)-(6E)-5-tert-butyldiphenylsilyloxy-7-formyl-6-heptenoate

ethyl (5S)-(6E)-5-tert-butyldiphenylsilyloxy-7-formyl-6-heptenoate

2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-O-isopropylidene-D-erythro-pentose diethyl dithioacetal

2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-O-isopropylidene-D-erythro-pentose diethyl dithioacetal

ethyl (5S)-(6E)-5-tert-butyldiphenylsilyloxy-7-formyl-6-heptenoate

ethyl (5S)-(6E)-5-tert-butyldiphenylsilyloxy-7-formyl-6-heptenoate

tert-Butyl-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-ynyloxy]-diphenyl-silane

tert-Butyl-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-ynyloxy]-diphenyl-silane

ethyl (5S)-(6E)-5-tert-butyldiphenylsilyloxy-7-formyl-6-heptenoate

ethyl (5S)-(6E)-5-tert-butyldiphenylsilyloxy-7-formyl-6-heptenoate

上游原料

2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-O-isopropylidene-D-erythro-pentose diethyl dithioacetal tert-Butyl-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-ynyloxy]-diphenyl-silane 2,2'-dimethyl-1-(4'(R)-1',3'-dioxacyclopentyl)-but-3-yn-1(S/R)-ol

下游产品

14-epi-LXB4 (6E,8E,10E,12E)-(5S,14R,15S)-5,14,15-Trihydroxy-icosa-6,8,10,12-tetraenoic acid (6E,8Z,10E,12E)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-13-((4S,5S)-2-oxo-5-pentyl-[1,3]dioxolan-4-yl)-trideca-6,8,10,12-tetraenoic acid ethyl ester (6E,8E,10E,12E)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-13-((4S,5S)-2-oxo-5-pentyl-[1,3]dioxolan-4-yl)-trideca-6,8,10,12-tetraenoic acid ethyl ester