百科

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

CAS号：98643-18-6

英文名：methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

分子式：C24H40O4

分子量：392.572

合成路线

(1S,2S,3S,4R)-3-tert-butyldimethylsilyloxymethyl-1-hydroxymethyl-2-(3-hydroxypropyl)-4-tetrahydropyranyloxycyclopentane

(1S,2S,3S,4R)-3-tert-butyldimethylsilyloxymethyl-1-hydroxymethyl-2-(3-hydroxypropyl)-4-tetrahydropyranyloxycyclopentane

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-6-(4,4-dimethyl-3-oxo-(E)-1-octenyl)-7-tetrahydropyranyloxybicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-6-(4,4-dimethyl-3-oxo-(E)-1-octenyl)-7-tetrahydropyranyloxybicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

(2bS,4R,5S,5aS)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-4-(tetrahydro-pyran-2-yloxy)-octahydro-2-oxa-cyclobuta[a]pentalen-1-ol

(2bS,4R,5S,5aS)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-4-(tetrahydro-pyran-2-yloxy)-octahydro-2-oxa-cyclobuta[a]pentalen-1-ol

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6S,7R)-6-hydroxymethyl-7-tetrahydropyranyloxybicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6S,7R)-6-hydroxymethyl-7-tetrahydropyranyloxybicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

5-[(3aS,5R,6R,6aS)-6-Formyl-5-(tetrahydro-pyran-2-yloxy)-1,3a,4,5,6,6a-hexahydro-pentalen-2-yl]-pentanoic acid methyl ester

5-[(3aS,5R,6R,6aS)-6-Formyl-5-(tetrahydro-pyran-2-yloxy)-1,3a,4,5,6,6a-hexahydro-pentalen-2-yl]-pentanoic acid methyl ester

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6S,7R)-6-tert-butyldimethylsilyloxymethyl-7-tetrahydropyranyloxybicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6S,7R)-6-tert-butyldimethylsilyloxymethyl-7-tetrahydropyranyloxybicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

98675-68-4

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(S)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

methyl (1R,5S,6R,7R)-7-hydroxy-6-<3(S)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoate

上游原料

(2bS,4R,5S,5aS)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-4-(tetrahydro-pyran-2-yloxy)-octahydro-2-oxa-cyclobuta[a]pentalen-1-ol methyl (1R,5S,6S,7R)-6-hydroxymethyl-7-tetrahydropyranyloxybicyclo<3.3.0>oct-2-ene-3-pentanoate 5-[(3aS,5R,6R,6aS)-6-Formyl-5-(tetrahydro-pyran-2-yloxy)-1,3a,4,5,6,6a-hexahydro-pentalen-2-yl]-pentanoic acid methyl ester (1S,2S,3S,4R)-3-tert-butyldimethylsilyloxymethyl-1-hydroxymethyl-2-(3-hydroxypropyl)-4-tetrahydropyranyloxycyclopentane methyl (1R,5S,6R,7R)-6-(4,4-dimethyl-3-oxo-(E)-1-octenyl)-7-tetrahydropyranyloxybicyclo<3.3.0>oct-2-ene-3-pentanoate methyl (1R,5S,6S,7R)-6-tert-butyldimethylsilyloxymethyl-7-tetrahydropyranyloxybicyclo<3.3.0>oct-2-ene-3-pentanoate

下游产品

(1R,5S,6R,7R)-7-hydroxy-6-<3(R)-hydroxy-4,4-dimethyl-(E)-1-octenyl>bicyclo<3.3.0>oct-2-ene-3-pentanoic acid